航空学报 > 1996, Vol. 17 Issue (2): 185-189

快速凝固Al94Ti4C2合金的显微组织和相结构分析

仝兴存1, 沈宁福1, 柳百成2   

  1. 1. 郑州工学院材料研究中心,郑州,450002;2. 清华大学机械系,北京,100084
  • 收稿日期:1994-09-30 修回日期:1994-12-08 出版日期:1996-04-25 发布日期:1996-04-25

ANALYSIS OF MICROSTRUCTURE AND INTERMETALLIC PHASES IN A RAPIDLY SOLIDIFIED AL94Ti4C2 ALLOY

Tong Xingcun1, Shen Ningf Liu Beicheng1   

  1. 1. Department of Mechanics, Tsinghua University, Beijing,100084;2. Research Center of M aterials, Zhengzhou Institute of Technology, Zhengzhou, 450002
  • Received:1994-09-30 Revised:1994-12-08 Online:1996-04-25 Published:1996-04-25

摘要: 研究了快速凝固 Al94Ti4C2 (at% )合金的显微组织和相结构特征。常规金属型铸态组织由分布于 α-Al基体中的片状 Al3Ti和以团簇形式存在的尺寸为 0 .3~ 1 μm的 Ti5C4 颗粒组成。经快速凝固以后 ,Ti5C4 分散为 2 0~ 40 nm的颗粒 ,接近连续地排列于α-Al晶粒边界 ;而 Al3Ti的形成受到抑制并为一有序 LI2 结构的亚稳相 (~ Al4 Ti)所替代 ,该相的晶格常数为 a0 ≈ 0 .40 4 nm,呈单个颗粒分居于每个 α-Al晶粒内 ,同 α-Al之间保持完全共格关系。以此为基础 ,对凝固过程特别是 Ti5C4 形成机制进行了分析和探讨

关键词: 固化, 铝合金, 相, 微观结构

Abstract: Intermetallic phases and microstructures of a rapidly solidified Al94Ti4C2(at%)alloy have been investigated. The DC casting microstructure comprises α Al, sheet like Al 3Ti and 0 3~1μm sized Ti 5C 4 particles appearing in the form of particle clusters. In the rapidly solidified alloy ribbons, the Ti 5C 4 phase disintegrates as fine particles of 20~40nm size, accumulating at and becoming trapped along the α Al grain boundaries, while Al 3Ti is replaced by an ordered LI 2 crystal structure (a 0≈0 404nm)metastable phase(~Al 4Ti),which is distributed in the α Al grains and retains a coherent lattice relationship with α Al matrix. Moreover, the formation mechanism of the intermetallic phase is discussed.

Key words: solidification, aluminum alloy phase, microstructure

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