航空学报 > 2009, Vol. 30 Issue (11): 2213-2217

Sm(CobalFe0.1Cu0.1Zr0.04)z(z=6.5~7.5)磁体的高温磁性能

许琦, 蒋成保, 张天丽   

  1. 北京航空航天大学 材料科学与工程学院
  • 收稿日期:2008-09-28 修回日期:2009-01-15 出版日期:2009-11-25 发布日期:2009-11-25
  • 通讯作者: 蒋成保

High Temperature Magnetic Property of Sm(CobalFe0.1Cu0.1Zr0.04)z(z=6.5~7.5) Magnets

Xu Qi, Jiang Chengbao, Zhang Tianli

  

  1. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics
  • Received:2008-09-28 Revised:2009-01-15 Online:2009-11-25 Published:2009-11-25
  • Contact: Jiang Chengbao

摘要: 在大功率航空发电机等领域,迫切需要研制使用温度超过450 ℃的高温永磁材料。然而,NdFeB永磁材料使用温度低于80 ℃,耐高温NdFeB永磁材料的使用温度也低于150 ℃;商业2∶17型Sm2Co17永磁体使用温度范围低于300 ℃。近年来,研制使用温度超过450 ℃的高温永磁材料成为该领域研究的热点问题。本文用粉末冶金的方法,制备了不同z值的Sm(CobalFe0.1Cu0.1Zr0.04)z(z=6.5~7.5)合金样品。系统研究了z值对合金结构、磁性能的影响规律。室温下z=7.3的合金矫顽力最大,超过2 400 kA/m;773 K时,z=7.1的合金矫顽力最大,达到640 kA/m。高温条件下合金的磁性能和退磁曲线的方形度降低。合金z值对内禀矫顽力温度系数影响显著,其中z=6.9的合金,内禀矫顽力温度系数最低,仅为-0.052%/℃,z≤6.7或z≥7.1时,均导致内禀矫顽力温度系数增大。

关键词: Sm(CobalFe0.1Cu0.1Zr0.04)z, 合金, 相组成, 高温性能, 磁性能, 内禀矫顽力, 内禀矫顽力温度系数

Abstract: There is a great demand for high temperature permanent magnet materials which are over 450 ℃ in temperature and can be used in highpower generators in the field of aviation. However, the temperatures for use of NdFeB permanent magnet materials are lower than 80 ℃. Even high temperature NdFeB permanent magnet materials can only be used at temperatures lower than 150 ℃. The temperature range of 2∶17Sm2Co17permanent magnets for business use is below 300 ℃. In recent years, the development of high temperature permanent magnetic materials with using temperatures exceeding 450 ℃ has become a hot issue in the field of study. In this article the Sm(CobalFe0.1Cu0.1Zr0.04)z(z=6.5~7.5)alloys are prepared by powder metallurgy. The effect of z value on the structure and magnetic properties of Sm(CobalFe0.1Cu0.1Zr0.04)z alloys is studied. The highest room temperature intrinsic coercivity iHc is achieved at more than 2 400 kA/m for z=7.3. A coercivity of more than 640 kA/m is obtained at 773 K for z=7.1. The temperature coefficient of coercivity is -0.052%/℃ forz=6.9. The temperature coefficient of coercivity increases forz≤6.7 or z≥7.1.

Key words: Sm(CobalFe0.1Cu0.1Zr0.04)z, alloys, phase component, high temperature properties, magnetic properties, intrinsic coercivity, temperature coefficient of coercivity

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