航空学报 > 2004, Vol. 25 Issue (4): 411-415

高性能M40J/BADCy复合材料的研究

任鹏刚, 梁国正, 杨洁颖, 王结良, 卢婷利   

  1. 西北工业大学理学院应用化学系 陕西西安 710072
  • 收稿日期:2003-07-07 修回日期:2003-12-15 出版日期:2004-08-25 发布日期:2004-08-25

Study on High Performance M40J/BADCy Composite

REN Peng-gang, LIANG Guo-zheng, YANG Jie-ying, WANG Jie-liang, LU Ting-li   

  1. Department of Applied Chemistry, School of Sciences, Northwestern Polytechnical University, Xi'an 710072, China
  • Received:2003-07-07 Revised:2003-12-15 Online:2004-08-25 Published:2004-08-25

摘要: 对E51环氧树脂改性双酚A型氰酸酯(BADCy)体系的力学性能及热性能进行了研究,发现当E51环氧树脂的质量含量为5%时,改性体系的弯曲强度和冲击强度分别由原来的95.6MPa和9.24kJ/m2提高到了117.8MPa和12.6kJ/m2,而热变形温度仅下降8℃。以该改性体系为基体制作的M40J复合材料,其弯曲强度、模量和剪切强度分别高达:1270MPa,172GPa,68 9MPa。消泡剂BYK141能提高M40J/BADCy复合材料的力学性能,层间剪切强度可提高到77.1MPa。M40J/BADCy复合材料还具有良好的耐环境能力,是一种理想的航空航天结构材料。

关键词: 聚合物基复合材料, 性能, 双酚A型氰酸酯, 环氧树脂, M40J碳纤维

Abstract: The mechanical and thermal properties of bisphenol A dicyanate(BADCy) modified by epoxy resin E51 are studied. It is found that, when 5% (mass fraction) epoxy resin E51 is introduced, the flexural strength and impact strength of BADCy can improve from 95.6MPa and 9.24kJ/m2 to 117.8MPa and 12.6kJ/m2, respectively, but the heat deformation temperature (HDT) of this system only descendes 8℃. The flexural strength, flexural modulus and inter-laminar shear strength of composite made from M40J and BADCy modified by 5% (mass fraction) epoxy resin E51 are as high as 1270MPa, 172GPa and 68.9MPa, respectively. Little amount of defoamer BYK 141 can improve the mechanical properties of M40J/BADCy composites. The inter-laminar shear strength(ILSS) is improved from 68.9MPa to 77.1MPa. Additionally, thanking to its excellent environment-resistant, M40J/BADCy composites are suitable for application of space structures.

Key words: polymer composite, property, bisphenol A dicyanate ester, epoxy resin, M40J carbon fiber