钎焊时间对CoFeNiCrCu高熵钎料钎焊SiC陶瓷接头组织与性能的影响

doi:10.7527/S1000-6893.2021.25057

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钎焊时间对CoFeNiCrCu高熵钎料钎焊SiC陶瓷接头组织与性能的影响

王秒¹, 王微², 杨云龙¹, 檀财旺³, 王刚¹

1. 安徽工程大学材料科学与工程学院, 芜湖 241000;
2. 安徽机电职业技术学院航空与材料学院, 芜湖 241002;
3. 哈尔滨工业大学材料科学与工程学院, 威海 264209

收稿日期:2020-12-04 修回日期:2020-12-21 出版日期:2022-04-15 发布日期:2021-03-01
通讯作者: 王刚 E-mail:gangwang@ahpu.edu.cn
基金资助:
安徽省杰出青年基金（2008085J23）；国家自然科学基金（51704001，52171148）；安徽省优秀拔尖人才培养重点项目（gxyqZD2020059）；安徽省领军骨干人才项目（Z175050020001）；安徽工程大学引进人才科研启动基金（2020YQQ036）；中国博士后科学基金（2021M690180）

Effect of brazing time on microstructure and properties of SiC ceramic brazed with CoFeNiCrCu

WANG Miao¹, WANG Wei², YANG Yunlong¹, TAN Caiwang³, WANG Gang¹

1. School of Materials Science and Engineering, Anhui Polytechnic University, Wuhu 241000, China;
2. School of Aviation and Materials, Anhui Machine and Electricity College, Wuhu 241002, China;
3. School of Materials Science and Engineering, Harbin Institute of Technology, Weihai 264209, China

Received:2020-12-04 Revised:2020-12-21 Online:2022-04-15 Published:2021-03-01
Supported by:
Natural Science Foundation of Anhui Province(2008085J23);National Natural Science Foundation of China (51704001,52171148);Talent and Top-notch Project of Anhui Province(gxyqZD2020059);Talent Project of Anhui Province (Z175050020001); Scientific Research Starting Foundation of Anhui Polytechnic University of China(2020YQQ036); China Postdoctoral Science Foundation(2021M690180)

摘要/Abstract

摘要： 采用CoFeNiCrCu高熵合金为钎料对SiC陶瓷进行了钎焊连接，研究了钎焊时间对接头微观组织和力学性能的影响。结果表明，SiC/CoFeNiCrCu/SiC接头的典型界面组织为：SiC/Cr₂₃C₆+Cu （s，s）+Si （s，s）/HEAF+Cu （s，s）/Cr₂₃C₆+Cu （s，s）+Si （s，s）/SiC。随着钎焊时间的增加，组织中相的种类没有发生变化，接头在高熵效应的作用下仍主要由固溶体组成，接头中反应层厚度逐渐增大。当钎焊时间为90 min时，反应层厚度达到最大为25 μm。但过厚的反应层使得接头在冷却过程中产生的应力在反应层中集中并导致反应层中产生裂纹等缺陷。当钎焊温度为1 180℃，保温60 min时，接头剪切强度最高达到61 MPa。此时，裂纹从远离接头的SiC陶瓷开始萌生并向接头方向扩展，最终断裂在陶瓷与反应层的界面处。

关键词: SiC陶瓷, 高熵钎料, 钎焊, 界面组织, 力学性能

Abstract: The SiC ceramic was brazed by CoFeNiCrCu filler, and the effect of brazing time on the microstructure and mechanical properties of the joint was investigated. The results show that the typical interface structure of the joint is SiC/Cr₂₃C₆+Cu(s, s)+Si(s, s)/HEAF+Cu(s, s)/Cr₂₃C₆+Cu(s, s)+Si(s, s)/SiC. With the increase of brazing time, no change of types of phases occurred in the structure; the joint was still mainly composed of solid solution due to the high entropy effect, but the thickness of the reaction layer in the joint gradually increased. When the brazing time was 90 min, the thickness of the reaction layer reached a maximum of 25 μm. However, the stress generated during the cooling process of the over thick reaction layer joint was concentrated in the reaction layer and caused defects such as cracks in the reaction layer. When the welding temperature was 1 180℃ and the holding time was 60 min, the maximum joint shear strength reached 61 MPa. At this time, cracks started from the SiC ceramic of the extended joint, and then expanded in the direction of the joint, and finally ruptured at the interface between the ceramic and the reaction layer.

Key words: SiC ceramic, high-entropy filler, brazing, interfacial microstructure, mechanical property

中图分类号:

V254.2

王秒, 王微, 杨云龙, 檀财旺, 王刚. 钎焊时间对CoFeNiCrCu高熵钎料钎焊SiC陶瓷接头组织与性能的影响[J]. 航空学报, 2022, 43(4): 525057-525057.

WANG Miao, WANG Wei, YANG Yunlong, TAN Caiwang, WANG Gang. Effect of brazing time on microstructure and properties of SiC ceramic brazed with CoFeNiCrCu[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2022, 43(4): 525057-525057.

参考文献

[1] TIAN W B, KITA H, HYUGA H, et al. Reaction joining of SiC ceramics using TiB₂-based composites[J]. Journal of the European Ceramic Society, 2010, 30(15):3203-3208.
[2] ZHOU X B, LIU J W, ZOU S R, et al. Almost seamless joining of SiC using an in-situ reaction transition phase of Y₃Si₂C₂[J]. Journal of the European Ceramic Society, 2020, 40(2):259-266.
[3] DONG H Y, YU Y D, JIN X L, et al. Microstructure and mechanical properties of SiC-SiC joints joined by spark plasma sintering[J]. Ceramics International, 2016, 42(13):14463-14468.
[4] RAKSHIT R, DAS A K. A review on cutting of industrial ceramic materials[J]. Precision Engineering, 2019, 59:90-109.
[5] 宋昌宝, 林铁松, 何鹏, 等. ZrC-SiC复合陶瓷扩散焊接头界面组织及力学性能[J]. 硅酸盐学报, 2014, 42(3):275-279. SONG C B, LIN T S, HE P, et al. Microstructure and mechanical property of diffusion bonded ZrC-SiC joint[J]. Journal of the Chinese Ceramic Society, 2014, 42(3):275-279(in Chinese).
[6] 冯广杰, 李卓然, 朱洪羽, 等. SiC陶瓷真空钎焊接头显微组织和性能[J]. 材料工程, 2015, 43(1):1-5. FENG G J, LI Z R, ZHU H Y, et al. Microstructure and mechanical property of vacuum brazed SiC ceramic joint[J]. Journal of Materials Engineering, 2015, 43(1):1-5(in Chinese).
[7] 蔡颖军, 王刚, 王微, 等. ZrB₂-SiC与Inconel 600钎焊接头组织及力学性能研究[J]. 兵器材料科学与工程, 2019, 42(3):35-39. CAI Y J, WANG G, WANG W, et al. Microstructure and mechanical properties of ZrB₂-SiC and Inconel 600 brazed joint[J]. Ordnance Material Science and Engineering, 2019, 42(3):35-39(in Chinese).
[8] 冯广杰, 李卓然, 徐慨, 等. SiC陶瓷真空钎焊接头界面结构及机理分析[J]. 焊接学报, 2014, 35(1):13-16. FENG G J, LI Z R, XU K, et al. Interface microstructure and mechanism of SiC ceramic vacuum brazed joint[J]. Transactions of the China Welding Institution, 2014, 35(1):13-16(in Chinese).
[9] RABIN B H. Joining of silicon carbide/silicon carbide composites and dense silicon carbide using combustion reactions in the titanium-carbon-nickel system[J]. Journal of the American Ceramic Society, 1992, 75(1):131-135.
[10] DAI X Y, CAO J, CHEN Z, et al. Brazing SiC ceramic using novel B₄C reinforced Ag-Cu-Ti composite filler[J]. Ceramics International, 2016, 42(5):6319-6328.
[11] QI Q, ZHANG J, HU H W, et al. Benefits of Zr additive element in the Ti₂₄Ni eutectic filler in vacuum brazing of SiC ceramics[J]. Vacuum, 2019, 162:110-113.
[12] WANG G, XIAO P, HUANG Z J, et al. Brazing of ZrB₂-SiC ceramic with amorphous CuTiNiZr filler[J]. Ceramics International, 2016, 42(4):5130-5135.
[13] BIAN H, SONG Y Y, LIU D, et al. Joining of SiO₂ ceramic and TC4 alloy by nanoparticles modified brazing filler metal[J]. Chinese Journal of Aeronautics, 2020, 33(1):383-390.
[14] WANG G, CAI Y J, WANG W, et al. AgCuTi/graphene-reinforced Cu foam:a novel filler to braze ZrB₂-SiC ceramic to Inconel 600 alloy[J]. Ceramics International, 2020, 46(1):531-537.
[15] BRIDGES D, ZHANG S H, LANG S, et al. Laser brazing of a nickel-based superalloy using a Ni-Mn-Fe-Co-Cu high entropy alloy filler metal[J]. Materials Letters, 2018, 215:11-14.
[16] 陈永星, 朱胜, 王晓明, 等. 高熵合金制备及研究进展[J]. 材料工程, 2017, 45(11):129-138. CHEN Y X, ZHU S, WANG X M, et al. Progress in preparation and research of high entropy alloys[J]. Journal of Materials Engineering, 2017, 45(11):129-138(in Chinese).
[17] ZHANG W R, LIAW P K, ZHANG Y. Science and technology in high-entropy alloys[J]. Science China Materials, 2018, 61(1):2-22.
[18] NAYAN N, SINGH G, MURTY S V S N, et al. Hot deformation behaviour and microstructure control in AlCrCuNiFeCo high entropy alloy[J]. Intermetallics, 2014, 55:145-153.
[19] JI W, WANG W M, WANG H, et al. Alloying behavior and novel properties of CoCrFeNiMn high-entropy alloy fabricated by mechanical alloying and spark plasma sintering[J]. Intermetallics, 2015, 56:24-27.
[20] ZHANG L X, SHI J M, LI H W, et al. Interfacial microstructure and mechanical properties of ZrB₂-SiC-C ceramic and GH99 superalloy joints brazed with a Ti-modified FeCoNiCrCu high-entropy alloy[J]. Materials & Design, 2016, 97:230-238.
[21] ZHANG Y, ZUO T T, TANG Z, et al. Microstructures and properties of high-entropy alloys[J]. Progress in Materials Science, 2014, 61:1-93.
[22] 李建国, 黄瑞瑞, 张倩, 等. 高熵合金的力学性能及变形行为研究进展[J]. 力学学报, 2020, 52(2):333-359. LI J G, HUANG R R, ZHANG Q, et al. Mechnical properties and behaviors of high entropy alloys[J]. Chinese Journal of Theoretical and Applied Mechanics, 2020, 52(2):333-359(in Chinese).
[23] WANG X F, ZHANG Y, QIAO Y, et al. Novel microstructure and properties of multicomponent CoCrCuFeNiTi_x alloys[J]. Intermetallics, 2007, 15(3):357-362.
[24] ZHU Z G, MA K H, WANG Q, et al. Compositional dependence of phase formation and mechanical properties in three CoCrFeNi-(Mn/Al/Cu) high entropy alloys[J]. Intermetallics, 2016, 79:1-11.
[25] LI H X, WANG Z Q, ZHONG Z H, et al. Micro-alloying effects of yttrium on the microstructure and strength of silicon carbide joint brazed with chromium-silicon eutectic alloy[J]. Journal of Alloys and Compounds, 2018, 738:354-362.
[26] LIU G W, MUOLO M L, VALENZA F, et al. Survey on wetting of SiC by molten metals[J]. Ceramics International, 2010, 36(4):1177-1188.
[27] SONG Y Y, LIU D, HU S P, et al. Graphene nanoplatelets reinforced AgCuTi composite filler for brazing SiC ceramic[J]. Journal of the European Ceramic Society, 2019, 39(4):696-704.
[28] ZHANG Y, ZOU G, LIU L, et al. Vacuum brazing of alumina to stainless steel using femtosecond laser patterned periodic surface structure[J]. Materials Science and Engineering:A, 2016, 662:178-184.
[29] YANG S Z, LI N, LI H. Effects of electric pulse treatment on shape memory effect and microstructure in a pre-deformation Fe₁₃Mn₆Si₁₃Cr₄Ni_0.1C alloy[J]. Rare Metal Materials and Engineering, 2016, 45(1):51-55.

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钎焊时间对CoFeNiCrCu高熵钎料钎焊SiC陶瓷接头组织与性能的影响

Effect of brazing time on microstructure and properties of SiC ceramic brazed with CoFeNiCrCu

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