航空学报 > 2008, Vol. 29 Issue (4): 1037-1043

用SAXS研究锂对7000系铝合金相变动力学的影响

魏芳1,2,李金山1,周铁涛3,刘培英3   

  1. 1西北工业大学 凝固国家重点实验室 2北京星航机电设备厂 3北京航空航天大学 材料科学与工程学院
  • 收稿日期:2007-06-12 修回日期:2008-01-15 出版日期:2008-07-10 发布日期:2008-07-10
  • 通讯作者: 魏芳1,2

Influence of Lithium on the Kinetics of Phase Transformation in 7000 Series Aluminum Alloy by SAXS Investigation

Wei Fang1,2, Li Jinshan1, Zhou Tietao3, Liu Peiying3   

  1. 1.State Key Laboratory of Solidification Processing, Northwestern Polytechnic University 2.Beijing Xinghang Mechanicalelectrical Equipment Factory 3.School of Materials Science and Engineering, Beijing University of Aeronautics andAstronautics
  • Received:2007-06-12 Revised:2008-01-15 Online:2008-07-10 Published:2008-07-10
  • Contact: Wei Fang1,2

摘要:

为了深入了解锂对7000系铝合金的影响,以获得优良性能含锂超高强铝合金,对含锂7000系铝合金进行了研究。采用小角X射线散射(SAXS)实验方法对7000系及含锂的7000系铝合金进行相变动力学研究,得出了析出相颗粒尺寸和体积分数。根据获得的这些数据进一步确定成核、长大和相变3个阶段的激活能。结果表明:含锂合金的析出相长大和粗化进程比无锂合金更加缓慢;含锂合金的成核激活能小于无锂合金,长大激活能和相变激活能都大于无锂合金,说明含锂合金析出相成核容易,长大和整个相变过程都比无锂合金困难。

关键词: SAXS, 7000系铝合金, 锂, 动力学, 析出相尺寸, 析出相体积分数, 激活能

Abstract:

To understand deeply the influence of lithium on 7000 series aluminum alloys, to obtain the Li-containing high strength alloys with good performance, the 7000 series Li-containing alloys are studied. The phase transformation kinetietics of the 7000 series Li-containing alloys containing lithium is investigated in comparison with Li-free 7000 series alloys by small angel X-ray scattering (SAXS) experimental measurements. The parameters for precipitate mean size and volume fraction are obtained by SAXS theory, and the activation energy for three stages is further obtained on the basis of the above information, including nucleus, growing and coarsening. The results show that as compared with Li-free alloys, the precipitation process of growing and coarsening is slower and nucleus activation energy is smaller, but the activation energy of growing and coarsening is larger in Li-containing alloys. It suggests that nucleus formation is easier, but the precipitation coruse of growing and coarsening is more difficult in Li-containing alloys than in Li-free alloys.

Key words: SAXS,  , 7000 , series , aluminium , alloy,  , Li,  , kinetics,  , precipitate , size,  , precipitate , volume , fraction,  , activation , energy

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