航空学报 > 2007, Vol. 28 Issue (增): 163-167

电子束物理气相沉积Nd2O3 和Yb2O3共掺杂的YSZ热障涂层研究

魏秋利,郭洪波,宫声凯   

  1. 北京航空航天大学 材料科学与工程学院
  • 收稿日期:2006-10-25 修回日期:2007-01-25 出版日期:2007-08-10 发布日期:2007-08-10
  • 通讯作者: 郭洪波

Research of Nd2O3 and Yb2OCo-doped YSZ Thermal Barrier Coatings Produced by Electron Beam Physical Vapor Deposition

WEI Qiu-li,GUO Hong-bo,GONG Sheng-kai   

  1. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics
  • Received:2006-10-25 Revised:2007-01-25 Online:2007-08-10 Published:2007-08-10
  • Contact: GUO Hongbo

摘要:

采用固相烧结的方法制备了10 mol% Nd2O3和Yb2O3共掺杂的YSZ(3-5 mol% Y2O3部分稳定的ZrO2)材料。掺杂材料为t/t′相,而8YSZ则为t/t′与m的混合相。测试结果表明:1 100 ℃时掺杂材料的热扩散系数为4.10×10-7m2/s,而8YSZ(8 wt% Y2O3部分稳定的ZrO2)的则为6.41×10-7 m2/s。在200~1 300 ℃温度范围内,掺杂材料的比热容均大大低于8YSZ。电子束物理气相沉积的掺杂材料的热障涂层陶瓷层为树枝晶结构。1 100 ℃下,掺杂材料的热障涂层热循环寿命为350~500 h,而同等条件下8YSZ涂层仅为 160~200 h。

关键词: 热障涂层, 电子束物理气相沉积, 比热容, 导热系数, 树枝晶

Abstract:

10 mol% Nd2O3 and Yb2O3 co-doped YSZ(3-5 mol% Y2O3 partially stabilized zirconia)was produced by a solid state sintering method.The doped material was t/t′ phase and YSZ was mixture of t/t′ and m phases.The thermal diffusion coefficient of the doped material was 4.10×10-7 m2/s and that of 8YSZ(8 wt.% Y2O3 partially stabilized zirconia)was 6.41×10-7m2/s at 1 100 ℃.The specific heat of the doped material was much lower than that of 8YSZ at the temperature between 2001 300 ℃.

Key words: TBCs,  , EB-PVD,  , specific , heat,  , thermal , conductivity, tree-like

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