ACTA AERONAUTICAET ASTRONAUTICA SINICA ›› 2023, Vol. 44 ›› Issue (11): 427656.doi: 10.7527/S1000-6893.2022.27656
• Material Engineering and Mechanical Manufacturing • Previous Articles
Tiangang ZHANG, Jiahao HUANG, Xiaoyun HOU, Zhiqiang ZHANG(
)
Received:2022-06-21
Revised:2022-07-07
Accepted:2022-08-12
Online:2023-06-15
Published:2022-08-31
Contact:
Zhiqiang ZHANG
E-mail:zqzhang@cauc.edu.com
Supported by:CLC Number:
Tiangang ZHANG, Jiahao HUANG, Xiaoyun HOU, Zhiqiang ZHANG. Mechanism for composite paint layer on aluminum alloy surface cleaned by laser[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2023, 44(11): 427656.
Table 6
EDS results of different surface areas in Fig.4
| 测试区域 | C | O | Mg | Si | Ti | Co | Pt | S | Al | Cu | Mn |
|---|---|---|---|---|---|---|---|---|---|---|---|
| A1 | 76.78 | 18.80 | 0.88 | 1.34 | 1.09 | 0.27 | 0.84 | ||||
| A2 | 23.97 | 48.42 | 9.62 | 10.54 | 4.65 | 1.84 | 0.96 | ||||
| B1 | 75.04 | 18.89 | 1.34 | 1.46 | 1.38 | 1.04 | 0.85 | ||||
| B2 | 43.02 | 36.24 | 0.99 | 1.08 | 1.26 | 1.21 | 0.79 | 2.97 | 12.44 | ||
| C1 | 76.68 | 18.21 | 1.09 | 0.83 | 0.99 | 1.05 | 0.81 | 0.34 | |||
| C2 | 31.53 | 41.25 | 0.62 | 0.63 | 0.91 | 0.98 | 0.71 | 2.96 | 20.41 | ||
| C3 | 23.32 | 12.77 | 1.22 | 0.82 | 0.73 | 1.01 | 0.72 | 0.44 | 58.18 | 0.58 | 0.21 |
Table 7
Positions and corresponding related structure of infrared bands of untreated paint layer[22-24]
| 振动频率/cm-1 | 振动模式 | 关联物质 |
|---|---|---|
| 3 356 | 醇羟基O—H伸缩 | 丙烯酸树脂 |
| 2 928 | CH2反对称伸缩 | 异氰酸酯 |
| 2 852 | CH2对称伸缩 | 异氰酸酯 |
| 1 725 | 酯羰基C=O伸缩 | 丙烯酸酯 |
| 1 683 | 羰基C=O伸缩(酰胺Ⅰ) | 氨基甲酸酯单元 |
| 1 520 | C—N—H弯曲振动(仲酰胺酰胺Ⅱ) | 氨基甲酸酯单元 |
| 1 449 | CH3不对称变角 | 丙烯酸酯 |
| 1 380 | CH3对称变角 | 丙烯酸酯 |
| 1 164 | 脂肪酸酯的C—O—C伸缩(与羰基C=O相连) | 丙烯酸酯 |
| 1 117 | 脂肪族仲胺C—N伸缩 | 异氰酸酯、氨基甲酸酯单元 |
| 1 086 | 醇类C—OH伸缩 | 丙烯酸酯 |
| 1 065 | 醇类C—OH伸缩 | 丙烯酸酯 |
| 1 018 | 脂肪酸酯的C—O—C伸缩(与烷基相连) | 丙烯酸酯 |
| 875 | 芳环C—H面外弯曲 | 芳烃溶剂 |
| 756 | N—H面外弯曲 | 氨基甲酸酯单元 |
| 730 | CH2面内摇摆 | 长链烷基 |
| 700 | 芳环C—H面外弯曲 | 芳烃溶剂 |
Table 8
Results of peak separation of XPS C1s spectra, binding energy and relative content before and after paint removal
| 状态 | 结合能/eV | 成分 | 相对含量/% |
|---|---|---|---|
| 除漆前 | 283.87 | C—H, C—C | 6.90 |
| 284.40 | —CH2—, C—C, C6H6 | 36.30 | |
| 284.73 | CH2C(CH3)(C(O)OH) n CH2C(CH3)(C(O)OCH3) n | 48.93 | |
| 286.18 | CH2C(CH3)(C(O)OCH3) n CH2C(CH3)(C(O)OCH2CH2OH) n | 5.05 | |
| 288.26 | O—C=O, O=C—N, C—N | 2.82 | |
| 540 mm/s除漆后 | 284.35 | i-CH3, C—H, —CH2— | 13.50 |
| 284.78 | 石墨碳, C, C—C, C—H CH2C(CH3)(C(O)OH) n CH2C(CH3)(C(O)OCH3) n CH2CH(C(O)OCH3) n | 58.52 | |
| 286.25 | CH2CH(C(O)OCH2CH3) n CH2CH(C(O)OCH3) n CH2C(CH3)(C(O)OCH2CH3) n | 20.16 | |
| 288.48 | O—C=O, O=C-N, C—N CH2C(CH3)(C(O)OCH2CH3) n CH2C(CH3)(C(O)OC(CH3)3 n | 7.82 |
Table 9
Results of peak separation of XPS O1s spectra, binding energy and relative content before and after paint removal
| 状态 | 结合能/eV | 成分 | 相对含量/% |
|---|---|---|---|
| 除漆前 | 530.41 | TiO2, MgO, SiO2, CoO | 16.10 |
| 530.91 | MgO, TiO2 | 15.49 | |
| 531.57 | CH2C(CH3)(C(O)OCH3) n C—O, —OH | 31.58 | |
| 532.22 | CH2C(CH3)(C(O)OCH3) n CH2C(CH3)(C(O)OCH2CH2OH) n CH2C(CH3)(C(O)OH) n | 24.17 | |
| 533.44 | —C=O, —COOC—, SiO2 | 11.25 | |
| 535.45 | —C=O | 1.41 | |
| 540 mm/s除漆后 | 530.41 | TiO2, MgO, SiO2, CoO, Al2O3 | 43.15 |
| 531.48 | TiO1.65, Al2O3, SiO2( Al2O3)0.22, C—O, —OH CH2C(CH3)(C(O)OCH3) n CH2C(CH3)(C(O)OCH2CH(CH3)2) n | 34.69 | |
| 532.48 | SiO2/Si, SiO2, SiO2(Al2O3)2.1 CH2CH(C(O)OCH3) n CH2CH(C(O)OH) n CH2C(CH3)(C(O)OH) n | 16.39 | |
| 533.52 | CH2CH(C(O)OCH2CH3) n CH2C(CH3)(C(O)OCH2CH3) n CH2C(CH3)(C(O)OCH2CH2OH) n | 5.77 |
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