高焓化学非平衡流条件下防热材料表面催化特性的试验方法

doi:10.7527/S1000-6893.2017.121317

ACTA AERONAUTICAET ASTRONAUTICA SINICA ›› 2017, Vol. 38 ›› Issue (10): 121317-121317.doi: 10.7527/S1000-6893.2017.121317

• Fluid Mechanics and Flight Mechanics • Previous Articles Next Articles

Test methods for determining surface catalytic properties of thermal protection materials in high enthalpy chemical non-equilibrium flows

LIU Liping^1,2, WANG Guolin², WANG Yiguang¹, MA Haojun², LUO Jie², ZHANG Jun²

1. Key Laboratory of Science and Technology on Thermostructural Composite Materials, Northwestern Polytechnical University, Xi'an 710072, China;
2. Hypervelocity Aerodynamics Institute, China Aerodynamics Research and Development Center, Mianyang 621000, China

Received:2017-04-12 Revised:2017-05-27 Online:2017-10-15 Published:2017-05-27
Supported by:
National Natural Science Foundation of China (51172181,11602289)

Abstract

Abstract:

The method for determining the surface catalytic recombination coefficients of Thermal Protection Materials (TPMs) in high enthalpy dissociated flows is established on 1 MW high frequency plasma wind tunnel according to the research development in diagnostics of high enthalpy chemical non-equilibrium flow and surface parameter determination of TPMs. This paper presents the catalytic recombination coefficient of SiO₂, with surface temperature being 1 563-2 003 K, enthalpy being 13.9-21.9 MJ/kg, and stagnation point pressure being 2.7, 5 and 10 kPa. The test results agree well with foreign literatures, indicating reliability of the method for determination of catalytic recombination coefficient. The method proposed can provide support for precise prediction of aerodynamic heat environment and more accurate design of TPMs.

Key words: high enthalpy chemical non-equilibrium flow, thermal protection materials, surface catalytic properties, test and evaluation, silicon dioxide, plasma wind tunnel

CLC Number:

V211.71

LIU Liping, WANG Guolin, WANG Yiguang, MA Haojun, LUO Jie, ZHANG Jun. Test methods for determining surface catalytic properties of thermal protection materials in high enthalpy chemical non-equilibrium flows[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2017, 38(10): 121317-121317.

References

[1] 崔尔杰. 近空间飞行器研究发展现状及关键技术问题[J]. 力学进展, 2009, 39(6):658-673. CUI E J. Research status development trends and key technical problems of near space flying vehicles[J]. Advances in Mechanics, 2009, 39(6):658-673(in Chinese).
[2] ANDERSON J D. Hypersonic and high-temperature gas dynamics[M]. New York:McGraw-Hill Book Company, 1989.
[3] 瞿章华. 高超声速空气动力学[M]. 长沙:国防科技大学出版社, 2001. QU Z H. Hypersonic aerodynamics[M]. Changsha:National University of Defence Technology Press, 2001(in Chinese).
[4] 徐华舫. 空气动力学基础[M]. 北京:国防工业出版社, 1979. XU H F. Fundamentals of aerodynamics[M]. Beijing:National Defence Industry Press, 1979(in Chinese).
[5] GOULARD R. On catalytic recombination rates in hypersonic stagnation heat transfer[J]. Journal of Jet Propulsion, 1958, 28(11):737-745.
[6] KUROTAKI T. Construction of catalytic model on SiO₂-based surface and application to real trajectory:AIAA-2000-2366[R]. Reston, VA:AIAA, 2000.
[7] STEWART D A, CHEN Y K, BAMFORD B J,et al. Predicting material surface catalytic effciency using arc-jet tests:AIAA-1995-2013[R]. Reston, VA:AIAA, 1995.
[8] SCOTT C D. Catalytic recombination of nitrogen and oxygen on high-temperature reusable surface insulation:AIAA-1980-1477[R]. Reston, VA:AIAA, 1980.
[9] KOVALEV V L, KOLESNIKOV A F. Experimental and theoretical simulation of heterogeneous catalysis in aerothermochemistry[J]. Fluid Dynamics, 2005, 40(5):669-693.
[10] VLASOV A V, ZALOGIN G N, ZEMLYANSKⅡ B A, et al. Methods and results of an experimental determi nation of the catalytic activity of materials at high temperatures[J]. Fluid Dynamics, 2003, 38(5):815-825.
[11] MATTHEW M, ERIC M, RONALD P, et al. Effect of surface catalysis on measured heat transfer in expansion tunnel facility[J]. Journal of Spacecraft and Rockets, 2013, 50(2):470-474.
[12] 孟松鹤, 金华, 王国林, 等. 热防护材料表面催化特性研究进展[J]. 航空学报, 2014, 35(2):287-302. MENG S H, JIN H, WANG G L, et al. Research advances on surface catalytic properties of thermal protection materials[J]. Acta Aeronautica et Astronautica Sinica, 2014, 35(2):287-302(in Chinese).
[13] NASUTI F, BRUNO C. Material-dependent catalytic recombination modeling for hypersonic flows:AIAA-1993-2840[R]. Reston, VA:AIAA,1993.
[14] BARBATO M. Modelling catalytic recombination heating at hypersonic speeds:AIAA-1989-0309[R]. Reston, VA:AIAA, 1989.
[15] KUROTAKI T, ITO T, MATSUZAKI T,et al. CFD evaluation of pressure effects on surface catalysis of SiO₂-based TPS:AIAA-2005-0388[R]. Reston, VA:AIAA, 2005.
[16] MIZUNO M, ITO T, MATSUZAKI T,et al. Experimental and numerical investigation of catalytic efficiency of atomic oxygen recombination on TPS surfaces:AIAA-2009-3934[R]. Reston, VA:AIAA, 2009.
[17] MARSCHALL J, FLETCHER D. Optical emission spectroscopy during plasmatron testing of ZrB2-SiC ultrahigh-temperature ceramic composites[J]. Journal of Thermophysics and Heat Transfer, 2009, 23(2):43-52.
[18] GREAVES J, LINNETT J. Recombination of atoms at surfaces. Part 6-Recombination of oxygen atoms on silica from 20℃ to 600℃[J].Transactions of the Faraday Society, 1959, 55(2):1355-1361.
[19] KIM Y C, BOUDART M. Recombination of O, N and H atoms on silica:Kinetics and mechanism[J]. Langmuir, 1991, 7:2999-3005.
[20] STEWART D A, LEISER D B,KOLODZIEJ P,et al. Thermal response of integral multicomponent composite thermal protection systems[J]. Journal of Spacecraft and Rockets, 1986, 23(4):420-427.
[21] SCOTT C D. Catalytic recombination of nitrogen and oxygen on iron-cobalt-chromia spinel:AIAA-1983-0585[R]. Reston, VA:AIAA,1983.
[22] WILLEY R J. Comparison of kinetic models for atom re-combination on high-temperature reusable surface insu-lation[J]. Journal of Thermophysics and Heat Transfer, 1993, 7(1):55-62.
[23] STEWART D A, RAKICH J V, LANFRANCO M J. Catalytic surfaces effects on space shuttle thermal protection system during earth entry of flights STS-2 through STS-5:NASA CP-2283[R]. Washington, D.C.:NASA, 1983.
[24] STEWART D A, KOLODZIEJ P, LEISER D B. Effect of variable surface catalysis on heating near stagnation point of a blunt body:AIAA-1985-0248[R]. Reston, VA:AIAA,1985.
[25] STEWART D A. Determination of surface catalytic efficiency for thermal protection materials-room temperature to their upper use limit:AIAA-1996-1863[R]. Reston, VA:AIAA,1996.

Test methods for determining surface catalytic properties of thermal protection materials in high enthalpy chemical non-equilibrium flows

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 5

Recommended Articles

Metrics

Comments

[1]	Zhifan YE, Jin ZHAO, Zhihui LI, Xiangchun SUN, Dongsheng WEN. Multiscale coupling simulation method for thermal protection material ablation based on thermochemical interfacial reactive model [J]. Acta Aeronautica et Astronautica Sinica, 2023, 44(S2): 729469-729469.
[2]	ZHAO Jin, SUN Xiangchun, ZHANG Jun, TANG Zhigong, WEN Dongsheng. Research advances on heat and mass transfer coupling effect at gas-solid interface for thermal protection materials [J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2022, 43(10): 527577-527577.
[3]	WU Dafang, LIN Lujin, WU Wenjun, SUN Chencheng. Thermal/vibration test of lightweight insulation material for hypersonic vehicle under extreme-high-temperature environment up to 1 500℃ [J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2020, 41(7): 223612-223612.
[4]	LIU Liping, WANG Guolin, WANG Yiguang, ZHANG Jun, LUO Lei. Catalytic performance of C/SiC composites in high enthalpy chemical non-equilibrium flow [J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2018, 39(5): 421696-421696.
[5]	MENG Songhe, JIN Hua, WANG Guolin, YANG Qiang, CHEN Hongbo. Research Advances on Surface Catalytic Properties of Thermal Protection Materials [J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2014, 35(2): 287-302.