航空学报 > 2021, Vol. 42 Issue (7): 424139-424139   doi: 10.7527/S1000-6893.2020.24139

TiC-TiB2复合相钛基稀土激光熔覆层组织与性能

张天刚1, 张倩2, 庄怀风3, 李宝轩3, 徐誉桐3   

  1. 1. 中国民航大学 民航技术研究院, 天津 300300;
    2. 中国民航大学 航空工程学院, 天津 300300;
    3. 中国民航大学 中欧航空工程师学院, 天津 300300
  • 收稿日期:2020-04-25 修回日期:2020-05-21 发布日期:2020-10-16
  • 通讯作者: 张天刚 E-mail:113099506@qq.com
  • 基金资助:
    国家自然科学基金(51371125);中央高校基本科研业务费专项资金(3122018D013);天津市研究生科研创新项目(2019YJSS077)

Microstructure and properties of TiC-TiB2 composite phase Ti-based rare earth laser cladding layers

ZHANG Tiangang1, ZHANG Qian2, ZHUANG Huaifeng3, LI Baoxuan3, XU Yutong3   

  1. 1. Institute of Civil Aviation Technology, Civil Aviation University of China, Tianjin 300300, China;
    2. College of Aeronautical Engineering, Civil Aviation University of China, Tianjin 300300, China;
    3. Sino-European Institute of Aviation Engineering, Civil Aviation University of China, Tianjin 300300, China
  • Received:2020-04-25 Revised:2020-05-21 Published:2020-10-16
  • Supported by:
    National Natural Science Foundation of China (51371125); The Fundamental Research Funds for the Central Universities (3122018D013); Tianjin Research Innovation Project for Postgraduate Students (2019YJSS077)

摘要: 采用通快同轴送粉4002光纤激光器,在TC4表面熔覆制备了不同含量Y2O3的TC4+Ni45+Co-WC+Y2O3钛基复合耐磨涂层。采用XRD、SEM、EDS、EPMA测试研究了涂层微观组织,利用显微硬度计、摩擦磨损实验机和白光轮廓仪分析评价了涂层的显微硬度和摩擦学性能。结果表明,涂层生成相不随Y2O3含量变化而改变,主要包括Ti2Ni、TiC、TiB2以及α-Ti;未添加Y2O3涂层,生成相尺寸粗大,方向性明显;随着Y2O3的加入,涂层组织逐步细化,生成相方向性减弱;当Y2O3为3wt%时,涂层析出相以颗粒和短棒状相为主,合成了大量TiC-TiB2依附生长复合相,经二维点阵错配度计算,TiB2(0001)与TiC (111)错配度δ为0.912%,TiC与TiB2形成了共格界面,可有效增加涂层组织分布均匀性;Y2O3含量为0wt%、1wt%和3wt%时,涂层显微硬度逐渐减小,磨损体积先增大后减小,摩擦系数逐渐降低;在TiC-TiB2复合相的作用下,3wt% Y2O3涂层的耐磨、减摩性最优,涂层磨损机理为磨粒磨损。

关键词: 激光熔覆, TC4, TiC-TiB2复合相, Y2O3, 二维点阵错配度, 摩擦磨损性能

Abstract: Wear-resistant TC4+Ni45+Co-WC+Y2O3 multi-channel overlapping Ti-based composite coatings with different Y2O3 mass fractions are cladded on TC4 by the TRUMPF 4002 coaxial powder feeding fiber laser. The microstructure of the coatings is tested and analyzed using XRD, SEM, EDS and EPMA. The microhardness and tribological properties of the coatings are analyzed by a microhardness tester, a friction and wear tester and a white light profiler. The results show that the phases in the coatings remain unchanged with different Y2O3 additions, mainly including Ti2Ni, TiC, TiB2 and α-Ti. In the coating without Y2O3, the phases are large in size with obvious directionality. With the addition of Y2O3, the microstructure of the coatings is gradually refined, and the directionality of the phases is weakened. When the Y2O3 addition is 3wt%, the precipitates in the coating are mainly particles and short rods, and a large number of TiC-TiB2 dependent growth composite phases are synthesized in the coating. Based on the two-dimensional lattice misfit calculation, the misfit δ between TiB2(0001) and TiC(111) is 0.912%, with TiC and TiB2 forming the coherent interface, thereby effectively increasing the distribution uniformity of the coating microstructure. With the addition of Y2O3, the microhardness of the coating decreases gradually, the wear volume of the coating first increases and then decreases, and the friction coefficient of the coating decreases gradually. The antifriction and wear resistance of the 3wt% Y2O3 coating are the best under the action of the TiC-TiB2 dependent growth composite phase, with the wear mechanism of the coating being abrasive wear.

Key words: laser cladding, TC4, TiC-TiB2 composite phase, Y2O3, two-dimensional lattice misfit, friction and wear properties

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