Abstract: A counter-flow air-fuel heat exchanger can be applied in an advanced aero engine to effectively decrease the high-pressure air temperature and thus recover its cooling capacity. However, the fuel, kerosene, is susceptible to thermal oxidative reactions in the heat exchange process, causing surface coking that would degrade the long-term heat exchange performance. Numerical studies have been conducted to investigate the long-term (15 h) heat exchange process between the supercritical-pressure (3 MPa) kerosene and high-pressure air (4 MPa) in a counter-flow heat exchanger, employing a detailed 35-step chemical reaction mechanism and a dynamic mesh moving method. The transient coking layer thickening process from thermal oxidative reactions was simulated, the coupled characteristics of thermal oxidative coking and heat exchange were analyzed under different air mass flow rates and dissolved oxygen mass fractions, and the effects of surface coking on the total heat transfer coefficient, number of transfer units (NTU), and effectiveness (ε) in the counter-flow heat exchanger were quantitatively evaluated. Results indicate that at an increased air mass flow rate, thus with the enhanced heat exchange rate, locations of the maximum surface coking rate and the entire coking layer inside the fuel tube move upstream, but the peak coking layer thickness remains essentially unchanged. The coking layer thickness in the middle and downstream regions can be significantly reduced as the dissolved oxygen mass fraction is decreased, improving heat exchange process in the corresponding regions. Gradual accumulation of the surface coking layer leads to heat exchanger performance deterioration, and a linear relationship is found to exist between the nondimensionalized NTU and nondimensionalized ε in the studied cases.
[1] DU W, LUO L, JIAO Y, et al. Heat transfer in the trail-ing region of gas turbines – a state-of-the-art review[J]. Applied Thermal Engineering, 2021, 199(1): 117614.
[2] 姬鹏飞. 典型管路RP-3航空煤油热氧化结焦沉积特性研究[D]. 南京: 南京航空航天大学, 2018:2-6.JI P F. Research on Autoxidation Coking Characteristics of Aviation Kerosene RP-3 in Typical Pipeline[D]. Nanjing: Nanjing University of Aeronautics and Astronautics, 2018:2-6(in Chinese).
[3] BRUENING G B, CHANG W S. Cooled cooling air systems for turbine thermal management[C]//Volume 3: Heat Transfer; Electric Power; Industrial and Cogenera-tion. Indianapolis, Indiana, USA: American Society of Mechanical Engineers, 1999: V003T01A002.
[4] 李勋锋, 仲峰泉, 范学军, 等. 超临界压力下航空煤油圆管流动和传热的数值研究[J]. 推进技术, 2010, 31(4): 467-472.LI X F, ZHONG F Q, FAN X J, et al. Numerical study of convective heat transfer of aviation kerosene flows in pipe at supercritical pressure[J]. Journal of Propulsion Technology, 2010, 31(4): 467-472(in Chinese).
[5] HUANG D, LI W. Heat transfer deterioration of aviation kerosene flowing in mini tubes at supercritical pres-sures[J]. International Journal of Heat and Mass Transfer, 2017, 111(1): 266-278.
[6] 刘志强. 空油换热器中航空燃料热氧化沉积机制及抑制方法[D]. 天津: 天津大学, 2022:1-2.LIU Z Q. Mechanism and inhibition method of thermal oxidation and deposition of jet fuel in air-fuel heat exchanger[D]. Tianjin: Tianjin University, 2022:1-2(in Chinese).
[7] SPADACCINI L J, SOBEL D R, HUANG H. Deposit formation and mitigation in aircraft fuels[J]. Journal of Engineering for Gas Turbines and Power, 2001,123(4): 741-746.
[8] 袁立公, 邓宏武, 徐国强, 等. 超临界压力下航空煤油RP-3壁面结焦特性对换热的影响[J]. 航空动力学报, 2013, 28(4): 832-837. YUAN L G, DENG H W, XU G Q, et al. Effect of Rp-3 coke deposition on heat transfer under supercritical pressure [J] Journal of Aerospace Power, 2013, 28(4): 832-837(in Chinese).
[9] LIU Z, YUAN S, GONG S, et al. Long-term thermal oxidative deposition of RP-3 jet fuels: mechanism and modeling[J]. Fuel, 2021, 303(1): 121250.
[10] JIA T, ZHANG X, LIU Y, et al. A comprehensive re-view of the thermal oxidation stability of jet fuels[J]. Chemical Engineering Science, 2021, 229(1): 116157.
[11] 王英杰, 徐国强, 邓宏武, 等. 进口温度影响航空煤油结焦特性实验[J]. 航空动力学报, 2009, 24(9): 1972-1976. WANG Y J, XU G Q, DENG H W, et al. Experimental study of influence of inlet temperature on aviation kerosene coking characteristics [J]. Journal of Aerospace Power, 2009, 24(9): 1972-1976(in Chinese).
[12] LIU Z, GONG S, WANG L, et al. Experimental investi-gation and modeling of thermal oxidation deposition of RP-3 jet fuel under high Reynolds number[J]. Fuel, 2022, 311(1): 122553.
[13] HAN Z, ZHOU W, ZHAO X, et al. Thermal oxidation deposition characteristics of RP-3 kerosene in serpentine tubes under supercritical pressure[J]. Fuel, 2022, 310(1): 122369.
[14] PEI X Y, Hou L Y. Effect of dissolved oxygen concen-tration on coke deposition of kerosene[J]. Fuel Pro-cessing Technology, 2016, 142(1): 86-91.
[15] 朱锟, 邓宏武, 徐国强, 等. 表面钝化对超临界航空煤油静态结焦特性影响[J]. 北京航空航天大学学报, 2012, 38(6): 745-749.ZHU K, DENG H W, XU G Q, et al. Surface passivation effect on the static coke deposition of kerosene at supercritical pressure [J]. Journal of Beijing University of Aeronautics and Astronautics, 2012, 38(6): 745-749(in Chinese).
[16] BALSTER L M, ZABARNICK S, STRIEBICH R C, et al. Analysis of polar species in jet fuel and determination of their role in autoxidative deposit formation[J]. Energy & Fuels, 2006, 20(6): 2564-2571.
[17] LIU Z, TANG S, LI Z, et al. An improved kinetic model for deposition by thermal oxidation of aviation hydrocar-bon fuels[J]. Fuel, 2019, 258(1): 116139.
[18] GIOVANETTI A J, SZETELA E J. Long-term deposit formation in aviation turbine fuel at elevated tempera-ture[J]. Journal of Propulsion and Power, 1986, 2(5): 450-456.
[19] PEI X, HOU L, ROBERTS W L. Experimental and numerical study on oxidation deposition properties of aviation kerosene[J]. Energy & Fuels, 2018, 32(7): 7444-7450.
[20] ERVIN J S, ZABARNICK S. Computational fluid dy-namics simulations of jet fuel oxidation incorporating pseudo-detailed chemical kinetics[J]. Energy & Fuels, 1998, 12(2): 344-352.
[21] YUAN Y, MENG H. Transient simulation of conjugate heat transfer of kerosene with thermal oxidative and sur-face coking reactions at a supercritical pressure[J]. Inter-national Journal of Thermal Sciences, 2024, 203(1): 109106.
[22] XING J, YU R, HAN H, et al. Study on the dynamic characteristics of thermal oxidation deposition of aviation kerosene under supercritical pressure[J]. Fuel, 2024, 357(1): 129874.
[23] YU R, ZOU X, HAN H, et al. Analysis of the effect of pyrolytic coking on the flow and heat transfer perfor-mance of n-decane in cooling channels at supercritical pressure[J]. International Journal of Heat and Mass Transfer, 2022, 195(1): 123147.
[24] 程泽源, 朱剑琴, 李海旺. 竖直圆管内超临界碳氢燃料换热恶化的直径效应[J]. 航空学报, 2016, 37(10): 2941-2951.CHENG Z Y, ZHU J Q, LI, H W. Diameter effect on heat transfer deterioration of supercritical hydrocarbon fuel in vertical round tubes[J]. Acta Aeronautica et Astronautica Sinica, 2016, 37(10): 2941-2951(in Chinese).
[25] BLOM F J. Considerations on the spring analogy[J]. International Journal for Numerical Methods in Fluids, 2000, 32(6): 647-668.
[26] XU K, MENG H. Analyses of surrogate models for calculating thermophysical properties of aviation kero-sene RP-3 at supercritical pressures[J]. Science China Technological Sciences, 2015, 58(3): 510-518.
[27] TAN T, YUAN Y, SUN X, et al. Computational study of heat exchange and thermal oxidative coking of su-percritical-pressure kerosene with compressed air in counterflows[J]. Journal of Thermal Science and Engi-neering Applications, 2023, 15(8): 81008.
[28] 英克鲁佩勒 F P,德维特 D P,伯格曼 T L,等. 传热和传质基本原理[M]. 葛新石,叶宏,译. 第六版. 北京: 化学工业出版社,2007:563-564.INCROPRERA F P, DEWITT D P, BERGMAN T L, et al. Fundamentals of Heat and Mass Transfer [M]. Ge X S, Ye H, translated. Sixth Edition. Beijing: Chemical Industry Press, 2007:563-564(in Chinese).
[29] HUANG X, WANG Q, SONG Z, et al. Heat transfer characteristics of supercritical water in horizontal dou-ble-pipe[J]. Applied Thermal Engineering, 2020, 173(1): 115191.