航空学报 > 2010, Vol. 31 Issue (4): 852-856

草酸钠体系中Ti-10V-2Fe-3Al钛合金阳极氧化膜的制备与表征

刘建华, 吴量, 李松梅, 于美, 易俊兰   

  1. 北京航空航天大学 材料科学与工程学院
  • 收稿日期:2009-03-12 修回日期:2009-06-15 出版日期:2010-04-25 发布日期:2010-04-25
  • 通讯作者: 刘建华

Preparation and Characterization of Anodic Oxide Film on Titanium AlloyTi-10V-2Fe-3Al in Sodium Oxalate Electrolyte

Liu Jianhua, Wu Liang, Li Songmei, Yu Mei, Yi Junlan   

  1. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics
  • Received:2009-03-12 Revised:2009-06-15 Online:2010-04-25 Published:2010-04-25
  • Contact: Liu Jianhua

摘要: 对Ti-10V-2Fe-3Al钛合金在草酸钠为主盐的新型无氟环保电解液体系中的阳极氧化进行了研究,成功制备出阳极氧化膜。采用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)等仪器研究了氧化膜的形貌、组成和相结构。采用电化学方法研究了阳极氧化后钛合金的耐腐蚀性能。结果表明:膜层具有多孔结构,孔径范围在80 nm~1 μm之间。膜层的主要成分是无定形的TiO2,同时有锐钛矿相及金红石相TiO2的存在。阳极氧化后钛合金的耐蚀性有显著的提高。

关键词: 草酸钠, 阳极氧化膜, Ti-10V-2Fe-3Al, 二氧化钛, 锐钛矿

Abstract: An anodic oxide film on titanium alloy Ti-10V-2Fe-3Al is prepared successfully in a new environment friendly electrolyte containing sodium oxalate. The microstructure, morphology and components of the oxide film are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS). Electrochemical measurement is employed to study the corrosion resistance of the titanium alloy after anodizing. It is shown that the film is porous, with pore sizes ranging from 80 nm to 1 μm. It is demonstrated that the components of the film are mainly amorphous titanium dioxide with some anatase and rutile phase. The corrosion resistance of the titanium alloy after anodizing is improved.

Key words: sodium oxalate, anodic oxide film, Ti-10V-2Fe-3Al, titanium dioxide, anatase

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