航空学报 > 2007, Vol. 28 Issue (1): 201-206

一种多元铌硅系原位复合材料的高温氧化行为

宋立国1,2,曲士昱2,宋尽霞2,李树索1,宫声凯1,韩雅芳1,2   

  1. 1. 北京航空航天大学 材料科学与工程学院, 2. 北京航空材料研究院
  • 收稿日期:2005-09-15 修回日期:2005-12-14 出版日期:2007-01-10 发布日期:2007-01-10
  • 通讯作者: 韩雅芳1,2

High temperature oxidation behavior of a multi-elements Nb-Si system in situ composite 

SONG Li-guo1,2,QU Shi-yu2,SONG Jing-xia2,LI Shu-suo1,GONG Sheng-kai1,HAN Ya-fang1,2   

  1. 1. School of Material Science & Engineering, Beijing University of Aeronautics and Astronautics,  2. Beijing Institute of Aeronautical Materials
  • Received:2005-09-15 Revised:2005-12-14 Online:2007-01-10 Published:2007-01-10
  • Contact: HAN Ya-fang1,2

摘要:

采用电弧熔炼的方法制备了Nb-16Si-24Ti-6Cr-6Al-2Hf (原子百分数)多元铌硅系原位复合材料。进行了高温氧化试验,使用扫描电镜、能谱和X-射线衍射仪进行分析。结果表明该复合材料铸态组织主要由Nbss和β-Nb5Si3组成;经1250℃/100h静态氧化后,生成厚的氧化皮,其主要成分为CrNbO4,TiNb2O7;在氧化皮下发生严重的内氧化现象;氧优先在Nbss相中扩散并形成内氧化产物;硅化物对氧的扩散起到一定的阻挡作用;硅化物的分散分布有利于氧化皮中压应力的释放。

关键词: Nb-Si系原位复合材料, 高温氧化, 氧化机理, 金属间化合物, 内氧化, Nb5Si3

Abstract:

A multi-elements Nb-Si-X system in situ composite with composition of Nb-16Si-24Ti-6Cr-6Al-2Hf (at%) was prepared by arc metlting method. The high temperature oxidation behavior of the alloy was investigated by scanning electron microscopy(SEM), energy dispersive spectrum(EDS) and X-ray diffraction(XRD). The as-cast composite consisted of Nbss phase and β-Nb5Si3 phase; After oxidation test at 1250℃ for 100h, the composite formed a thick scale being mainly composed of CrNbO4 and TiNb2O7, below which severe inner oxidation occurred.

Key words: Nb-Si , system , in , situ , composite, high , temperature , oxidation, oxidation , mechanism,  , intermetallic,  , inner , oxidation,  , Nb5Si3

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