航空学报 > 1981, Vol. 2 Issue (1): 95-104

应力腐蚀和氢致裂纹机构

褚武扬, 李世琼, 肖纪美, 朱淑彦   

  1. 北京钢铁学院
  • 收稿日期:1979-08-01 修回日期:1900-01-01 出版日期:1981-03-25 发布日期:1981-03-25

MECHANISM OF STRESS CORROSION CRACKING AND HYDROGEN INDUCED CRACKING

Zhu Wuyang, Li Shiqiong, Xiao Jimei, Zhu Shuyan   

  1. Beijing Insiiiuie of Iron and Sieel Technology
  • Received:1979-08-01 Revised:1900-01-01 Online:1981-03-25 Published:1981-03-25

摘要: 用抛光的恒位移试样对不同强度的四种低合金钢在各种致氢环境(如电解充氢,H2和H2S气体,水.H2S水溶液等)下,跟踪观察了应力腐蚀裂纹和氢致滞后裂纹的产生和扩展过程。结果表明,当钢的强度和K1大于临界值后,在任何一种致氢环境中都能产生氢致滞后塑性变形,即随着原子氢的扩散进入,原裂纹前端塑性区及其变形量逐渐增大。当这个氢致滞后塑性变形发展到临界状态时,就会导致氢致滞后裂纹的形核和扩展。 用光滑拉伸试样,弯曲试样,Ⅰ型,Ⅲ型以及Ⅰ-Ⅲ复合型预裂纹试样研究了氢对表观屈服强度的影响。结果表明,对光滑拉伸和预裂纹扭转试样,氢对屈服强度的影响是不明显的。但如试样中存在拉应力梯度(如弯曲试样,Ⅰ型或复合型预裂纹试样),当钢的强度和进入的氢量超过临界值时,氢就能明显地降低表观屈服强度,这就是氢致滞后塑性变形的原因。根据表观屈服强度对进入的氢量和强度的依赖关系,可以解释Klscc和da/dt对强度和环境的依赖关系。 研究了变形速度,试验温度以及预先塑性变形程度对氢致表观屈服强度下降的影响。在此基础上探讨了氢使表现屈服强度下降的原因。

Abstract: The nucleation and propagation of stress corrosion cracking(SCC) and hydrogen-induced delayed cracking(HIDC) in various hydrogenant environments, such as H2S and H2 gases, water, aqueous solution of H2S and charging were followed metallographically, using polished WOL type constant deflection specimen. The results of investigation show that if KI>KI cc and the strength of steel is larger than a critical value, the size of the plastic zone and the degree of plastic deformation ahead of the crack is enlarged continuously with time, i. e. a hydrogen-induced delayed plasticity(HIDP) is observed and SCC and HIDC then nucleate and propagate when HIDP develops to a critical condition. For charging specimen, HIDC nucleated preferentially on the surface of a specimen, then HIDP on the surface of the specimen was not caused by pre-produced crack in the interior of the specimen.The effect of hydrogen on the apparent yield strength of a smooth tensile and precrack twist specimen are insignificant. However, for the bending or I and I -III complex precrack specimen with a tensile stress gradient, hydrogen decreases the apparent yield stress considerably if the strength of steel and amount of hydrogen exceed critical values. This is the cause of HIDP and then HIDC. The variation of the KI sec and da/dt with the strength of steel and the environments has been explained.The effect of loading rate, test temperature and pre-plastic deformation on hydrogen induced apparent yield stress reduction have been investigated. According to these results, a new mechanism of SCC or HIDC in low-alloy steels has been discussed.