ACTA AERONAUTICAET ASTRONAUTICA SINICA >
One-step electrical explosion preparation of nitrogen-doped graphite and its microwave absorption properties
Received date: 2025-09-09
Revised date: 2025-10-04
Accepted date: 2025-11-10
Online published: 2025-12-23
Supported by
National Natural Science Foundation of China(52262012);Key Research and Development Plan of Gansu Province(25YFGA025);State Key Laboratory of Special Rare Metal Materials, China Nonferrous Metal (Ningxia) Orient Group Co., Ltd(SKL2021K001);The Postdoctoral Program at Station of Gansu(23JRRA762);University Young Doctor Support Program in Gansu Province in 2023(2023QB-051)
Graphene exhibits significant application potential due to its excellent electrical conductivity and low density. However, the inability of pristine graphene to satisfy impedance matching criteria limits its application in the electromagnetic wave absorption field. Currently, nitrogen doping can optimize the microwave absorption properties of graphene, but the preparation process is complicated and accompanied by the generation of organic waste liquids that cause environmental pollution. Therefore, replacing graphene low-cost graphite to fabricate carbon-based wave-absorbing composite holds considerable research value. In this study, the nitrogen-doped graphite as electromagnetic wave-absorbing materials were prepared by a one-step electrical explosion method under nitrogen-argon (N2-Ar) mixed atmospheres with different volume ratios. Experimental results demonstrate the the nitrogen-doped graphite prepared under a 50vol% N2-Ar mixed atmosphere achieves a minimum Reflection Loss (RL) value of -50.40 dB. When the thickness is 1.30 mm, its maximum Effective Absorption Bandwidth (EAB) reaches 4.24 GHz, and the Radar Cross-Section (RCS) reduction value attains 36.46 dB m2. The one-step electrical explosion method for preparing the nitrogen-doped graphite provides a new insight for the design of low-cost electromagnetic wave-absorbing materials.
Yupeng WEI , Lele LIU , Rongpeng GUO , Yixuan DA , Meng ZHANG , Zhengqi LU , Xuebing YAN , Hui ZHOU , Xudong WANG , Liang ZHU . One-step electrical explosion preparation of nitrogen-doped graphite and its microwave absorption properties[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2026 , 47(12) : 432766 -432766 . DOI: 10.7527/S1000-6893.2025.32766
| [1] | ZHANG S J, LAN D, ZHENG J J, et al. Perspectives of nitrogen-doped carbons for electromagnetic wave absorption[J]. Carbon, 2024, 221: 118925. |
| [2] | HOU Z L, GAO X S, ZHANG J Y, et al. A perspective on impedance matching and resonance absorption mechanism for electromagnetic wave absorbing [J]. Carbon, 2024, 222: 118935. |
| [3] | LUO W L, SUN Y, LIN Z T, et al. Flexible Ti3C2T x MXene/V2O5 composite films for high-performance all-solid supercapacitors [J]. Journal of Energy Storage, 2023, 62: 106807. |
| [4] | LUO W L, LIU Q W, ZHANG B Z, et al. Binder-free flexible Ti3C2T x MXene/reduced graphene oxide/carbon nanotubes film as electrode for asymmetric super-capacitor [J]. Chemical Engineering Journal, 2023, 474: 145553. |
| [5] | LUO W L, SUN Y, HAN Y Q, et al. Flexible Ti3C2T x MXene/polypyrrole composite films for high-performance all-solid asymmetric supercapacitors[J]. Electrochimica Acta, 2023, 441: 141818. |
| [6] | WANG C J, ZHANG B Z, SUN X Y, et al. Fabrication of core-shell Fe3O4@polypyrrole@sodium dodecyl benzene sulfonate composite for high-performance adsorption of methylene blue and malachite green in water[J]. Separation and Purification Technology, 2024, 329: 125140. |
| [7] | ZHAO R, LIANG B Q, SHI Y X, et al. Recent progress of carbon-based magnetic fibers for electromagnetic wave absorption[J]. Carbon, 2024, 229: 119513. |
| [8] | QU N, XU G X, LIU Y K, et al. Multi-scale design of metal-organic framework metamaterials for broad-band microwave absorption[J]. Advanced Functional Materials, 2024, 35(18): 2402923. |
| [9] | WANG Y, DI X C, LU Z, et al. Controllable heterogeneous interfaces of cobalt/carbon nanosheets/rGO composite derived from metal-organic frameworks for high-efficiency microwave attenuation[J]. Carbon, 2022, 187: 404-414. |
| [10] | REN X H, WANG J T, YIN H F, et al. Hierarchical CoFe2O4@PPy hollow nanocubes with enhanced micro-wave absorption [J]. Applied Surface Science, 2022, 575: 151752. |
| [11] | XU J, SHU R W, WAN Z L, et al. Construction of three-dimensional hierarchical porous nitrogen-doped reduced graphene oxide/hollow cobalt ferrite composite aerogels toward highly efficient electromagnetic wave absorption[J]. Journal of Materials Science Technology, 2023, 132: 193-200. |
| [12] | YAO H D, ZHAO N N, HUANG D, et al. Ni/Al?O? structures on defective carbon coating derived from pyrolysis of nitrogen-enriched coal tar pitch for acetylene hydrogenation[J]. Chemical Engineering Journal, 2025, 519: 165245. |
| [13] | BARRAZA-GARCíA F, LóPEZ-URíAS F, PéREZ-MIRANDA S, et al. P-N transition in nitrogen-doped MWCNTs synthesized from DMF/toluene precursors via aerosol assisted-chemical vapor deposition[J]. Carbon, 2025, 243: 120579. |
| [14] | TARIQ M R, KHAN I, AHMAD M, et al. Fabrication of polydopamine doped helical/chiral porous carbon fiber (HPCFs@PDA) and N-doped carbon layers (HPCFs@ NCLs) for their application as wave absorber with ultrawide EAB[J]. Diamond and Related Materials, 2025, 151: 111774. |
| [15] | NIE S H, WANG Z, JIANG X H, et al. Nitrogen-doped eugenol-group polymer carbon microspheres with high-performance microwave (2-18 GHz) absorption[J]. Materials Today Communications, 2025, 44: 112061. |
| [16] | TIAN L L, XIE Y L, LU J, et al. Self-assembled 3D Fe3O4/N-Doped graphene aerogel composite for large and fast lithium storage with an excellent cycle performance[J]. Journal of Electroanalytical Chemistry, 2022, 922: 116763. |
| [17] | WU Z, YAO X K, XING Y Q. A review of nitrogen-doped graphene aerogel in electromagnetic wave absorption[J]. Micromachines, 2023, 14(9): 1762. |
| [18] | FU K L, ZHAO J B, LIU F, et al. Enhanced electromagnetic wave absorption of nitrogen-doped reduced graphene oxide aerogels with LaFeO3 cluster modifications [J]. Carbon, 2023, 210: 118071. |
| [19] | SHU R W, XU J, SHI J J. Construction of nitrogen-doped graphene-based ternary magnetic composite aerogel towards excellent electromagnetic absorption in the Ku-band[J]. Journal of Alloys and Compounds, 2023, 956: 170349. |
| [20] | SHU R W, XU J, SHI J J. Synthesis of nitrogen-doped graphene-based binary composite aerogels for ultralight-weight and broadband electromagnetic absorption[J]. Ceramics International, 2023, 49(18): 30214-30223. |
| [21] | LIANG L W, WU J, WANG B, et al. Microstructure and electromagnetic wave absorption properties of FeCo/graphene composites prepared by electrical wire explosion method[J]. Applied Surface Science, 2025, 681: 161577. |
| [22] | LI C, HAN R Y, GENG J Y, et al. One-step preparation of pure and Cu-decorated graphite thin layers via electrical explosion in a confined environment: Physical process and product characterization[J]. Ceramics International, 2022, 48(14): 19874-19881. |
| [23] | LI C, HAN R Y, BAI J, et al. One-step synthesis of structural-controlled metal-graphene nanocomposites via flash atomization and plasma-assisted reactions of electrical explosion[J]. Carbon, 2023, 213: 118296. |
| [24] | HAN R Y, LI C, GAO M, et al. Graphite and bismuth selenide under electrical explosion in confined environment: Exfoliation, phase transition, and surface decoration[J]. Advanced Materials Interfaces, 2023, 10(5): 2201568. |
| [25] | WANG X D, ZHOU H, WEI Y P, et al. Electrical explosion spray of Ag/C composite coating and its deposition behavior[J]. Ceramics International, 2022, 48(4): 4497-4504. |
| [26] | WANG X D, WEI Y P, ZHOU H, et al. Synthesis of graphene nanosheets by the electrical explosion of graphite powder confined in a tube[J]. Ceramics International, 2021, 47(15): 21934-21942. |
| [27] | LI X H, SHU Y, ZHAO T K, et al. Electromagnetic wave absorption property of crosslinked holey Fe/FeO/Fe2O3/ RGO nanocomposite[J]. Ceramics International, 2025, 51(3): 2974-2984. |
| [28] | YE X L, ZHANG H Y, YU H, et al. Synergistic design of C/SiC@SiC aerogel for enhanced thermal insulation and electromagnetic wave absorption[J]. Ceramics International, 2024, 50(21): 43023-43031. |
| [29] | 褚海荣, 周梦雨, 时双强, 等. 还原氧化石墨烯吸波性能及宽频优化[J]. 材料工程, 2025, 53(3): 117-124. |
| CHU H R, ZHOU M Y, SHI S Q, et al. Microwave absorption performance and broadband absorption optimization of reduced graphene oxide[J]. Journal of Materials Engineering, 2025, 53(3): 117-124 (in Chinese). | |
| [30] | MENG L Z, WANG J H, QI J Y, et al. Yolk-shell construction of Co0.7Fe0.3 modified with dual carbon for broadband microwave absorption[J]. Journal of Colloid and Interface Science, 2024, 659: 945-958. |
| [31] | HANG T Y, ZHOU L J, LI Z H, et al. Constructing gradient reflection and scattering porous framework in composite aerogels for enhanced microwave absorption [J]. Carbohydrate Polymers, 2024, 329: 121777. |
| [32] | TANG W K, DONG S, CUI T Y, et al. Lightweight zirconium modified carbon-carbon composites with excellent microwave absorption and mechanical properties[J]. Composites Part A: Applied Science and Manufacturing, 2024, 180: 108102. |
| [33] | ZHANG M, QIAN C, ZHU R T, et al. Flower-like MoS2 self-assembled on multiferroic Z-type Sr3Co2Fe24O41 hexaferrite for ultra-wideband microwave absorption[J]. Journal of Alloys and Compounds, 2022, 926: 166881. |
| [34] | YANG H L, LI C Q, MO R W, et al. Facile preparation and broadband microwave absorption of multilayered materials based on thin films of reduced graphene oxide [J]. Carbon, 2024, 224: 119093. |
| [35] | YANG Y, QIAN C, HU P Q, et al. Nitrogen-doped core-shell Fe/Fe3C@C nanocomposites for electromagnetic wave absorption [J]. Journal of Materials Science: Materials in Electronics, 2023, 34: 1847. |
| [36] | TIAN S Y, LI A R, CUI J B, et al. Order effect of nitrogen and phosphorus co-doping carbon nanofibers for enhancing electromagnetic wave absorption[J]. Carbon, 2023, 203: 580-589. |
| [37] | BAI L, CHANG N, ZHAO M Y, et al. Broadband absorption performance of 3D-printed polyetheretherketone-based electromagnetic wave-absorbing composites[J]. Chinese Journal of Aeronautics, 2024, 37(8): 547-558. |
| [38] | 叶永盛, 丁迪, 吴海华, 等. 石墨烯增强Fe3O4/乙基纤维素复合微球吸波性能[J]. 航空学报, 2023, 44(11): 427549. |
| YE Y S, DING D, WU H H, et al. Graphene-enhanced Fe3O4/ethylcellulose composite microspheres with wave absorption properties[J]. Acta Aeronautica et Astronautica Sinica, 2023, 44(11): 427549 (in Chinese). | |
| [39] | TANG K K, LONG F H, ZHANG F H, et al. Research progress on high-temperature-resistant electromagnetic wave absorbers based on ceramic materials: A review[J]. Nanomaterials, 2025, 15(4): 268. |
| [40] | XIE Y P, JI L, YUAN H, et al. Lamellar rGO/g-C3N4 nanosheets composites for electromagnetic wave absorption[J]. Chemical Physics Letters, 2025, 878: 142358. |
| [41] | SHI L, JIANG H T, ZHANG X M, et al. Facile synthesis of CoFe/C nanoparticle embedded in nitrogen and sulfur co-doped reduced graphene oxide nanocomposites for electromagnetic wave absorption[J]. Applied Surface Science, 2025, 682: 161765. |
| [42] | DONG Y Q, LI C S, ZHANG S T, et al. Prussian blue derived N-doped porous carbon/Fe4N/rGO for broadband electromagnetic wave absorption[J]. Ceramics International, 2025, 51(3): 3413-3422. |
| [43] | WANG L, MAO R X, HUANG M Q, et al. Heterogeneous interface engineering of high-density MOFs-derived Co nanoparticles anchored on N-doped RGO toward wide-frequency electromagnetic wave absorption [J]. Materials Today Physics, 2023, 35: 101128. |
| [44] | ZHOU J, CHEN Y J, LI H, et al. Facile synthesis of three-dimensional lightweight nitrogen-doped graphene aerogel with excellent electromagnetic wave absorption properties[J]. Journal of Materials Science, 2017, 53(6): 4067-4077. |
| [45] | XU D W, ZHANG M J, SHEN Z H, et al. Salt template assisted preparation of magnetic modified nitrogen doping hollow carbon microcapsules for broadband microwave absorption[J]. Journal of Alloys and Compounds, 2025, 1014: 178721. |
| [46] | ZHOU Y, ZHANG W, PAN D, et al. Absorption-reflection-transmission power coefficient guiding gradient distribution of magnetic MXene in layered composites for electromagnetic wave absorption[J]. Nano Micro Letters, 2025, 17: 147. |
| [47] | SHU R W, ZHANG G Y, ZHANG C, et al. Nitrogen-doping-regulated electromagnetic wave absorption properties of ultralight three-dimensional porous reduced graphene oxide aerogels[J]. Advanced Electronic Materials, 2021, 7(2): 2001001. |
| [48] | WAN Z L, SHU R W, ZHANG J B, et al. Synthesis of three-dimensional porous nitrogen-doped reduced graphene oxide/multi-walled carbon nanotubes composite aerogel as lightweight and high-performance electro- magnetic wave absorbers[J]. Diamond and Related Materials, 2021, 112: 108245. |
| [49] | XIONG X H, ZHANG H B, LV H L, et al. Recent progress in carbon-based materials and loss mechanisms for electromagnetic wave absorption[J]. Carbon, 2024, 219: 118834. |
| [50] | QIAO J, LI L T, LIU J R, et al. The vital application of rare earth for future high-performance electromagnetic wave absorption materials: A review[J]. Journal of Materials Science Technology, 2024, 176: 188-203. |
| [51] | SHU R W, NIE L J, LIU X Y, et al. Fabrication of nitrogen-doped reduced graphene oxide/tricobalt tetraoxide composite aerogels with high efficiency, broadband microwave absorption, and good compression recovery performance[J]. Journal of Materials Science Technology, 2024, 190: 106-116. |
| [52] | LIU Z, WANG B, WEI S C, et al. Novel preparation of FeCo alloy/graphene foam composites for efficient microwave absorption[J]. Carbon, 2023, 215: 118452. |
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