Material Engineering and Mechanical Manufacturing

Impact of Ru Buffer Layer on Diffusion Behavior Between NiCoCrAlY and Single Crystal Superalloy DD6

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  • 1. School of Materials Science and Engineering, Beihang University, Beijing 100191, China;
    2. AVIC Shenyang Liming Aero-engine(Group)Corporation Ltd., Shenyang 110043, China

Received date: 2010-07-24

  Revised date: 2010-08-25

  Online published: 2011-04-25

Abstract

In this paper, a metallic protective coating is investigated as a diffusion barrier on the second generation single crystal superalloy DD6. A double layer of NiCoCrAlY/Ru coating is prepared by electroplating and electron beam physical vapor deposition (EB-PVD) on a sample of single crystal superalloy DD6. Also, a single NiCoCrAlY coating is deposited onto the single crystal superalloy by EB-PVD. The results show that an interdiffusion zone (IDZ) of ~55 μm and a secondary reaction zone (SRZ) of ~25 μm are formed in the superalloy after 300 h heat-treatment at 1 050 ℃ in atmospheric environment. Compared with the single NiCoCrAlY coating, the NiCoCrAlY/Ru coating effectively suppressed the formation of SRZ in the superalloy. There are only tiny amounts of topologically close-packed phases (TCP) precipitated in the superalloy.

Cite this article

WANG Juan, PENG Hui, CHEN Guozhong, GUO Hongbo, GONG Shengkai. Impact of Ru Buffer Layer on Diffusion Behavior Between NiCoCrAlY and Single Crystal Superalloy DD6[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2011, 32(4): 758-764. DOI: CNKI:11-1929/V.20101110.1442.001

References

[1] Miller R A. Thermal barrier coatings for aircraft engines: history and directions [J]. Journal of Thermal Spray Technology, 1997, 6(1): 35-42.

[2] Rigney D V, Vigule V, Wortman D J. PVD thermal barrier coating applications and process development for aircraft engines [J]. Journal of Thermal Spray Technology, 1997, 6(2): 167-175.

[3] Padture N P, Gell M, Jordan E H. Thermal barrier coatings for gas-turbine applications [J]. Science, 2002, 296: 280-284.

[4] Stiger M J, Yanar N M, Topping M G. Thermal barrier coatings for the 21st century [J]. Materials Research and Advanced Techniques, 1999, 12: 1069-1087.

[5] 李美栓. 金属的高温腐蚀[M]. 北京: 冶金工业出版社, 2001: 420-431. Li Meishuan. High temperature corrosion of alloy[M]. Beijing: Metallurgical Industry Press, 2001: 420-431. (in Chinese)

[6] Brindley W J, Miller R A. Thermal barrier coating life and isothermal oxidation of low-pressure plasma-sprayed bond coat alloys [J]. Surface and Coatings Technology, 1990, 43(1-3): 446-457.

[7] Angenete J, Stiller K, Bakchinova E. Microstructural and microchemical development of simple and Pt-modified aluminide diffusion coatings during long term oxidation at 1 050 ℃ [J]. Surface and Coatings Technology, 2004, 176(3): 272-283.

[8] Chen J H, Little J A. Degradation of the platinum aluminide coating on CMSX4 at 1 100 ℃ [J]. Surface and Coatings Technology, 1997, 92(1-2): 69-77.

[9] Walston W S, Schaeffer J C, Murphy W H. A new type of microstructural instability in superalloys—SRZ //Proceedings of the 8th International Symposium on Superalloys 1996. 1996: 9-18.

[10] Matsuoka Y, Aoki A, Matsumoto K, et al. The formation of SRZ on a fourth generation single crystal superalloy applied with aluminide coating //Proceedings of Superalloys 2004. 2004: 637-642.

[11] Karunaratne M S A, Rae C M F, Reed R C. On the microstructural instability of an experimental nickel base single crystal superalloy[J]. Metallurgical and Materials Transactions A, 2001, 32(10): 2409-2421.

[12] Rae C M F, Reed R C. The precipitation of topologically close-packed phase in rhenium-containing superalloys [J]. Acta Materialia, 2001, 49(19): 4113-4125.

[13] Pollock T M, Murphy W H, Goldman E H. Grain defect formation during directional solidification of nickel base single crystals//Proceedings of Superalloys 1992. 1992: 125-134.

[14] Tryon B, Cao F, Murphy K S, et al. Ruthenium-containing bond coats for thermal barrier coating systems[J]. The Journal of Metals, 2006, 58(1): 53-59.

[15] Wang Q M, Wu Y N, Guo M H, et al. Ion-plated Al-O-N and Cr-O-N films on Ni-base superalloys as diffusion barriers[J]. Surface and Coatings Technology, 2005, 197(1): 68-76.

[16] Wang Y, Guo H B, Li H F, et al. Manufacturing and microstructure of RuAl/NiAl diffusion barrier coating for Ni-based single crystal superalloy substrate //Proceedings of 6th International Conference on Materials Processing for Properties and Performance. 2007: 9.

[17] 王开国, 李嘉荣, 刘世忠, 等. DD6单晶高温合金760℃的蠕变性能研究[J]. 材料工程, 2004(5): 7-11. Wang Kaiguo, Li Jiarong, Liu shizhong, et al. Study on creep properties of single crystal superalloy DD6 at 760℃[J]. Material Engineering, 2004(5): 7-11. (in Chinese)

[18] Das D K, Murphy K S, Ma S, et al. Formation of secondary reaction zones in diffusion aluminide-coated Ni-base single-crystal superalloys containing ruthenium [J]. Metallurgical and Materials Transactions A, 2008, 39(7): 1647-1657.

[19] Nystrom J D, Pollock T M, Murphy W H, et al. Discontinuous cellular precipitation in a high-refractory nickel-base superalloy [J]. Metallurgical and Materials Transactions A, 1997, 28(12): 2443-2452.

[20] 刘刚,刘林,赵新宝,等. 难熔元素对镍基单晶高温合金凝固特性及组织的影响[J]. 材料导报,2008, 22(9): 38-42. Liu Gang, Liu Lin, Zhao Xinbao, et al. Influence of refractory elements addition on solidification characteristics and microstructure of Ni-based single-crystal superalloys [J]. Materials Review, 2008, 22(9): 38-42. (in Chinese)

[21] Sinha A K. Topologically close-packed structures of metal alloys [M]. Longdon: Pergamon, 1972: 18-46.

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