氮掺杂石墨的一步电爆法制备及吸波性能研究

  • 魏玉鹏 ,
  • 刘乐乐 ,
  • 路钲淇 ,
  • 郭荣鹏 ,
  • 张萌 ,
  • 颜学冰 ,
  • 达怡萱 ,
  • 周辉 ,
  • 王旭东 ,
  • 朱亮
展开
  • 1. 兰州理工大学
    2. 兰州工业学院材料工程学院
    3. 兰州理工大学材料科学与工程学院

收稿日期: 2025-09-09

  修回日期: 2025-11-12

  网络出版日期: 2025-12-23

基金资助

国家自然科学基金;西北稀有金属材料研究院宁夏有限公司稀有金属特种材料国家重点实验室开放课题基金;甘肃省重点研发计划-工业领域

One-step electrical explosion preparation of nitrogen-doped graphite and its microwave absorption properties

  • WEI Yu-Peng ,
  • LIU Le-Le ,
  • LU Zheng-Qi ,
  • GUO Rong-Peng ,
  • ZHANG Meng ,
  • YAN Xue-Bing ,
  • DA Yi-Xuan ,
  • ZHOU Hui ,
  • WANG Xu-Dong ,
  • ZHU Liang
Expand

Received date: 2025-09-09

  Revised date: 2025-11-12

  Online published: 2025-12-23

摘要

石墨烯因其优异的电导率和低密度具有很大的应用潜力,但单一石墨烯因无法满足阻抗匹配的要求,限制其在电磁波吸收领域的应用。目前氮掺杂可以优化石墨烯的微波吸收性能,然而其制备工艺繁杂且制备过程中伴随着环境污染的有机废液,因此采用低成本石墨替代石墨烯简便制备碳基吸波复合材料,具有重要的研究价值。通过一步电爆炸法在不同比例氮氩混合气氛中制备出氮掺杂石墨电磁波吸收材料。实验结果表明:在50 vol.%氮氩混合气氛下制备的氮掺杂石墨最小反射损耗值为-50.40 dB。在厚度为1.30 mm时,其最大有效吸收频宽可达4.24 GHz,雷达反射截面(RCS)缩减值达到36.46 dB m2。一步电爆法制备氮掺杂石墨为低成本电磁波吸波材料的设计提供新思路。

本文引用格式

魏玉鹏 , 刘乐乐 , 路钲淇 , 郭荣鹏 , 张萌 , 颜学冰 , 达怡萱 , 周辉 , 王旭东 , 朱亮 . 氮掺杂石墨的一步电爆法制备及吸波性能研究[J]. 航空学报, 0 : 1 -0 . DOI: 10.7527/S1000-6893.2025.32766

Abstract

Graphene exhibits great application potential due to its excellent electrical conductivity and low density; however, the inability of pristine graphene to satisfy impedance matching criteria limits its application in the electromagnetic wave absorption field. Currently, nitrogen doping can optimize the microwave absorption properties of graphene, but the preparation process is complicated and accompanied by the generation of organic waste liquids that cause environmental pollution. Therefore, Carbonbased wave-absorbing composites using low-cost graphite as a substitute for graphene via a simple preparation route holds significant research value. The nitrogen-doped graphite as electromagnetic wave-absorbing materials were prepared by a one-step electrical explosion method under nitrogen-argon (N?-Ar) mixed atmospheres with different volume ratios. The nitrogen-doped graphite prepared under a 50 vol.% N?-Ar mixed atmosphere achieves a minimum reflection loss (RL) value of -50.40 dB. When the thickness is 1.30 mm, its maximum effective absorption bandwidth (EAB) reaches 4.24 GHz, and the radar cross-section(RCS)reduction value attains 36.46 dB m2. The one-step electrical explosion method for preparing the nitrogen-doped graphite provides a new insight for the design of low-cost electromagnetic wave-absorbing materials.
文章导航

/