利用光学显微镜研究了置氢处理后Ti-6Al-4V合金的微观组织,通过X射线衍射分析试验研究了置氢处理过程中的相转变过程;采用室温压缩试验研究了置氢处理后Ti-6Al-4V合金的变形行为,并进行了冷镦试验。结果表明,氢促进了α″马氏体与亚稳β相的形成,亚稳β相的形成与转变是Ti-6Al-4V合金变形性能提高的主要因素;在氢含量为0.60%~0.90%时,与原始合金相比,峰值应力降低60 MPa,压缩极限提高40%以上;氢含量为0.80%时,通过冷镦成型制备了直径为φ10 mm的Ti-6Al-4V合金90°沉头螺钉。
The microstructure of hydrogenated Ti-6Al-4V alloy is studied by an optical microscope, and its phase transformations are analyzed during the hydrogenating treatment by X-ray diffraction(XRD). The deformation behavior of the hydrogenated Ti-6Al-4V alloy is investigated through compression tests at room temperature, and jumptests are performed, too. The results show that the presence of hydrogen in the alloy promotes the formation of martensite α″ and metastable phase β, and the formation and transition of metastable phase β is the major factor for the improvement of processability of Ti-6Al-4V alloy. Compared with the as-received alloy, the peak stress of hydrogenated Ti-6Al-4V with 0.60% H to 0.90% H decreases by 60 MPa and its compression limit improves by over 40%. When the hydrogen content reaches 0.80%, 90°sunk screws of diameter φ 10 mm can be prepared from Ti-6Al-4V by alloy jumptests at room temperature.
[1] 毛进勤. 我国应积极发展高品质钛合金紧固件[J]. 世界有色金属, 2008(4): 64-67. Mao Jinqin. Emphasizing the development of high-qualified titanium alloy fastener industry in China[J]. World Nonferrous Metals, 2008(4):64-67. (in Chinese)
[2] 张庆玲, 王庆如, 李兴无. 航空用钛合金紧固件选材分析[J]. 材料工程, 2007(1):11-18. Zhang Qingling, Wang Qingru, Li Xingwu. Materials selection analysis for titanium alloy fasteners in aviation industry[J]. Journal of Materials Engineering, 2007(1):11-18. (in Chinese)
[3] 周芸, 王超. 钛合金紧固件生产技术[J]. 钛工业进展, 2001(1):12-15. Zhou Yun, Wang Chao. Manufacturing technique of titanium fastener[J]. Titanium Industry Progress,2001(1):12-15. (in Chinese)
[4] Senkov O N, Froes F H. Thermohydrogen processing of titanium alloys[J]. International Journal of Hydrogen Energy, 1999, 24(6):565-576.
[5] Goltsov V A. Hydrogen treatment (processing) of materials: current status and prospects[J]. Journal of Alloys and Compounds, 1999, 293-295:844-857.
[6] 侯红亮, 李志强, 王亚军, 等. 钛合金热氢处理技术及其应用前景[J]. 中国有色金属学报, 2003, 13(3):533-549. Hou Hongliang, Li Zhiqiang, Wang Yajun, et al. Technology of hydrogen treatment for titanium alloy and its application prospect[J]. The Chinese Journal of Nonferrous Metals, 2003, 13(3):533-549. (in Chinese)
[7] Zhang S Q, Zhao L R. Effect of hydrogen on the superplasticity and microstructure of Ti-6Al-4V alloy[J]. Journal of Alloys and Compounds, 1995,218(2): 233-236.
[8] Zong Y Y, Shan D B, Lu Y,et al. Effect of 0.3wt% H addition on the high temperature deformation behaviors of Ti-6Al-4V alloy[J]. International Journal of Hydrogen Energy, 2007, 32(16): 3936-3940.
[9] Feng J C, Liu H, He P, et al. Effects of hydrogen on diffusion bonding of hydrogenated Ti6Al4V alloy containing 0.3 wt% hydrogen at fast heating rate[J]. International Journal of Hydrogen Energy, 2007, 32(14): 3054-3058.
[10] 宁兴龙. 钛合金的可逆氢合金化[J]. 钛工业进展,1995(1): 19-20. Ning Xinglong. Reversible hydrogen of titanium alloy[J]. Titanium Industry Progress, 1995(1): 19-20. (in Chinese)
[11] Ilyin A A, Nosov V K, Kollerov M U, et al. Hydrogen technology of semifinished products and finished goods production from high-strength titanium alloys//Advances in the Science and Technology of Titanium Alloy Processing. Warrendale, PA: TMS, 1996: 517-523.
[12] 孙中刚, 侯红亮, 李红, 等. 氢处理对TC4钛合金组织及室温变形性能的影响[J]. 中国有色金属学报, 2008, 18(5):789-793. Sun Zhonggang, Hou Hongliang, Li hong, et al. Effect of hydrogen treatment on microstructure and room temperature deforming properties of TC4 Ti alloy[J]. The Chinese Journal of Nonferrous Metals, 2008, 18(5):789-793. (in Chinese)
[13] 李晓华, 孙中刚, 侯红亮, 等. 置氢Ti-6Al-4V合金组织与室温变形行为的相关性[J]. 北京科技大学学报, 2008, 30(8):888-892. Li Xiaohua, Sun Zhonggang, Hou Hongliang, et al. Correlation between microstructure and room-temperature deformation behavior of the hydrogenated Ti-6Al-4V alloy[J]. Journal of University of Science and Technology Beijing, 2008, 30(8):888-892. (in Chinese)
[14] 李红, 侯红亮, 孙中刚. 氢对TC4钛合金室温压缩行为的影响[J]. 航空制造技术, 2007(z1):80-83. Li Hong, Hou Hongliang, Sun Zhonggang. The effect of hydrogen treatment on the room temperature compression behaviour of TC4[J]. Aeronautical Manufacturing Tech-nology, 2007(z1):80-83. (in Chinese)
[15] 张喜燕, 赵永庆, 白晨光, 等. 钛合金及应用[M]. 北京:化学工业出版社, 2005:91. Zhang Xiyan, Zhao Yongqing, Bai Chenguang, et al. Titanium alloy and its applications[M]. Beijing: Chemical Industry Press, 2005:91. (in Chinese)
[16] 吴晓东, 杨冠军, 葛鹏, 等. β钛合金及其固态相变的归纳[J]. 钛工业进展, 2008, 25(5):1-6. Wu Xiaodong, Yang Guanjun, Ge Peng, et al. Inductions of β titanium alloy and solid state phase transition[J]. Titanium Industry Progress, 2008, 25(5):1-6. (in Chinese)
[17] 李兴无, 沙爱学, 储俊鹏, 等. 淬火温度对Ti-3Al-4.5V-5Mo钛合金形变诱发马氏体的影响[J]. 材料工程, 2007(9):3-8. Li Xingwu, Sha Aixue, Chu Junpeng, et al. Effect of quenching temperature on deformation-induced martensite of Ti-3Al-4.5V-5Mo titanium alloy[J]. Journal of Materials Engineering, 2007(9):3-8. (in Chinese)