航空学报 > 2004, Vol. 25 Issue (5): 508-512

界面相对3D-C/SiC复合材料热膨胀性能的影响

张青, 成来飞, 张立同, 徐永东   

  1. 西北工业大学凝固技术国家重点实验室 陕西西安 710072
  • 收稿日期:2003-07-31 修回日期:2003-12-15 出版日期:2004-10-25 发布日期:2004-10-25

Effects of Interphases on Thermal Expansion of 3D-C/SiC Composites

ZHANG Qing, CHENG Lai-fei, ZHANG Li-tong, XU Yong-dong   

  1. State Key Laboratory of Solidification Processing , Northwestern PolytechnicalUniversity , Xi'an 710072 , China
  • Received:2003-07-31 Revised:2003-12-15 Online:2004-10-25 Published:2004-10-25

摘要: 利用减压化学气相浸渗(LPCVI)技术制备了3D C/SiC复合材料,从热解碳(PyC)界面相厚度对界面结合强度和热应力的影响出发,研究了界面相对复合材料热膨胀性能的影响。结果表明:①界面相厚度对3D C/SiC复合材料热膨胀性能的影响主要归因于其对界面结合强度和脱黏面上的滑移阻力的影响。在一定厚度范围(约70~220nm)内,材料的热膨胀系数随热解碳厚度的增加而逐渐降低;②热处理可提高材料的热稳定性,并通过改变材料内部结构,使热应力重新分布,对复合材料的高温热膨胀产生显著影响,但是,并没有改变基体裂纹的愈合温度(900℃)。

关键词: 3DC/SiC复合材料, 界面热应力, 热膨胀性能, 热解碳界面相, 化学气相浸渗

Abstract: 3D-C/SiC composites with PyC interphase in different thickness were fabricated by low pressure chemical vapour infiltration (LPCVI),and the effect of PyC interphase thickness on thermal expansion of 3D-C/SiC composites is studied. It is shown that the effect of interphase thickness on thermal expansion of 3D-C/SiC composites lies in its influence on interphase bonding strength and sliding resistance in the debonding layer. In a certain thickness range (about 70-220nm),coefficient of thermal expansion (CTE) of the composites decreases gradually with increasing of PyC interphase thickness. Moreover,heat treatment improves the thermal stability of the composites,and influences the CTE by changing interfacial thermal stress and microstructure of the composites, and changes CTE of the composites intensively at high temperatures by changing interfacial thermal stress and microstructure of materials. However,heat treatment does not change the matrix crack sealed temperature.

Key words: 3D-C/SiC composite, interfacial thermal stress, thermal expansion, PyC interphase, CVI