ACTA AERONAUTICAET ASTRONAUTICA SINICA >
Optimal design of fracture toughness for CNT⁃epoxy composites
Received date: 2023-05-08
Revised date: 2023-06-02
Accepted date: 2023-07-11
Online published: 2023-07-14
Supported by
Postdoctoral Fellowship Program of CPSF(GZC20232263);Young Scientist Fund of National Natural Science Foundation of China(52305165)
Compared with carbon fiber, Carbon Nanotube (CNT) is the ideal reinforcement phase for the epoxy composites,which has higher mechanical properties and lower density and, the great potential application in the aerospace field. A processing scheme was proposed for the CNT-epoxy Single-Edge Notched Bend (SENB) specimens, and the measuring methods of microscopic structure and parameters were proposed. The fracture toughness tests were conducted on the SENB specimens with different MWCNT lengths and oxidation times. The effects of the interfacial length and interfacial C—C bond density on the fracture toughness were quantitatively analyzed, and the fracture toughness optimization scheme was proposed. The experimental results show that: the interfacial C—C bond density and ozone oxidation time of CNTs show linear relationship; the relative fracture toughness enhancement rate increases rapidly with the increase of the ozone oxidation time, and then decreases dramatically. This means that there exists a critical interfacial C—C bond density, where the relative fracture toughness enhancement rate reaches maximum; for the weak interface, the relative fracture toughness enhancement rate increases rapidly with the increase of the interfacial length, and then decreases slightly; for the strong interface, the relative fracture toughness enhancement rate increases rapidly with the increase of the interfacial length, and then decreases dramatically; the fracture toughness reaches maximum, when the amounts of CNT pullout and CNT fracture are approximately equal,which means that the fracture toughness reaches maximum under the transition condition of the failure mode from the CNT pullout to CNT fracture.
Wenbin JIA , Lei FANG , Gen ZHANG , Jian SHI , Zekan HE , Haijun XUAN . Optimal design of fracture toughness for CNT⁃epoxy composites[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2024 , 45(7) : 428971 -428971 . DOI: 10.7527/S1000-6893.2023.28971
1 | WENG J M, WEN W D, ZHANG H J. Multiaxial fatigue life prediction of composite materials[J]. Chinese Journal of Aeronautics, 2017, 30(3): 1012-1020. |
2 | JIA W B, WEN W D, FANG L. Low-velocity impact and post-impact biaxial residual strength tests and simulations of composite laminates[J]. Composite Structures, 2020, 235: 111758. |
3 | JIA W B, WEN W D, FANG L. Damage initiation and propagation in composites subjected to low-velocity impact: Experimental results, 3D dynamic damage model, and FEM simulations[J]. Transactions of Nanjing University of Aeronautics and Astronautics, 2019, 36(3): 488-499. |
4 | 李军,刘燕峰,倪洪江,等.航空发动机用树脂基复合材料应用进展与发展趋势[J].材料工程,2022,50(6):49-60. |
LI J, LIU Y F, NI H H, et al. Application progress and development trend of resin matrix composites for aero engine[J]. Journal of Materials Engineering, 2022, 50(6): 49-60 (in Chinese). | |
5 | 刘大响. 一代新材料, 一代新型发动机: 航空发动机的发展趋势及其对材料的需求[J]. 材料工程, 2017, 45(10): 1-5. |
LIU D X. One generation of new material, one generation of new type engine: Development trend of aero-engine and its requirements for materials[J]. Journal of Materials Engineering, 2017, 45(10): 1-5 (in Chinese). | |
6 | GAUR U, MILLER B. Microbond method for determination of the shear strength of a fiber/resin interface: Evaluation of experimental parameters[J]. Composites Science and Technology, 1989, 34(1): 35-51. |
7 | GIANOLA D S, EBERL C. Micro- and nanoscale tensile testing of materials[J]. JOM, 2009, 61(3): 24-35. |
8 | HUANG M Y, YAN H G, CHEN C Y, et al. Phonon softening and crystallographic orientation of strained graphene studied by Raman spectroscopy[J]. Proceedings of the National Academy of Sciences of the United States of America, 2009, 106(18): 7304-7308. |
9 | 陈玉丽, 马勇, 潘飞, 等. 多尺度复合材料力学研究进展[J]. 固体力学学报, 2018, 39(1): 1-68. |
CHEN Y L, MA Y, PAN F, et al. Research progress in multi-scale mechanics of composite materials[J]. Chinese Journal of Solid Mechanics, 2018, 39(1): 1-68 (in Chinese). | |
10 | TANG L C, ZHANG H, HAN J H, et al. Fracture mechanisms of epoxy filled with ozone functionalized multi-wall carbon nanotubes[J]. Composites Science and Technology, 2011, 72(1): 7-13. |
11 | TANG L C, ZHANG H, WU X P, et al. A novel failure analysis of multi-walled carbon nanotubes in epoxy matrix[J]. Polymer, 2011, 52(9): 2070-2074. |
12 | CHEN Y L, LIU B, HE X Q, et al. Failure analysis and the optimal toughness design of carbon nanotube-reinforced composites[J]. Composites Science and Technology, 2010, 70(9): 1360-1367. |
13 | 亚斌. 碳纳米管增强复合材料的制备与力学性能研究[D]. 大连: 大连理工大学, 2016. |
YA B. Research on the preparation and mechanical properties of carbon nanotubes reinforced composites[D].Dalian: Dalian University of Technology, 2016 (in Chinese). | |
14 | 施雪军, 任一丹. 碳纳米管/环氧树脂复合材料的导热及力学性能[J]. 平顶山学院学报, 2020, 35(5): 39-42. |
SHI X J, REN Y D. Thermal conductivity and mechanical properties of carbon nanotubes/epoxy resin composites[J]. Journal of Pingdingshan University, 2020, 35(5): 39-42 (in Chinese). | |
15 | 王卫芳, 陆宝山, 耿哲. 环氧树脂/石墨烯/多壁碳纳米管复合材料力学性能研究[J]. 塑料科技, 2019, 47(7): 24-27. |
WANG W F, LU B S, GENG Z. Study on mechanical properties of EP/GNP/MWCNT composites[J]. Plastics Science and Technology, 2019, 47(7): 24-27 (in Chinese). | |
16 | 王颖, 梅园, 李颖, 等. 表面改性对螺旋碳纳米管/环氧树脂复合材料力学性能的影响[J]. 高分子材料科学与工程, 2018, 34(10): 40-45. |
WANG Y, MEI Y, LI Y, et al. Effect of surface modification of helical carbon nanotubes on the mechanical properties of epoxy composites[J]. Polymer Materials Science and Engineering, 2018, 34(10):40-45 (in Chinese). | |
17 | MA P C, SIDDIQUI N A, MAROM G, et al. Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review[J]. Composites Part A: Applied Science and Manufacturing, 2010, 41(10): 1345-1367. |
18 | CHA J, KIM J, RYU S, et al. Comparison to mechanical properties of epoxy nanocomposites reinforced by functionalized carbon nanotubes and graphene nanoplatelets[J]. Composites Part B: Engineering, 2019, 162: 283-288. |
19 | DATSYUK V, KALYVA M, PAPAGELIS K, et al. Chemical oxidation of multiwalled carbon nanotubes[J]. Carbon, 2008, 46(6): 833-840. |
20 | DEPLANCKE T, LAME O, BARRAU S, et al. Impact of carbon nanotube prelocalization on the ultra-low electrical percolation threshold and on the mechanical behavior of sintered UHMWPE-based nanocomposites[J]. Polymer, 2017, 111: 204-213. |
21 | VIET N V, WANG Q, KUO W S. Effective Young’s modulus of carbon nanotube/epoxy composites[J]. Composites Part B: Engineering, 2016, 94: 160-166. |
22 | WANG H, XIE G Y, FANG M H, et al. Mechanical reinforcement of graphene/poly(vinyl chloride) composites prepared by combining the in-situ suspension polymerization and melt-mixing methods[J]. Composites Part B: Engineering, 2017, 113: 278-284. |
23 | CHEN Y L, WANG S T, LIU B, et al. Effects of geometrical and mechanical properties of fiber and matrix on composite fracture toughness[J]. Composite Structures, 2015, 122: 496-506. |
24 | KINLOCH I A, SUHR J, LOU J, et al. Composites with carbon nanotubes and graphene: An outlook[J]. Science, 2018, 362(6414): 547-553. |
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