Interfacial microstructure and mechanical properties of TiB2-TiC-SiC ceramics joints fabricated by contact reactive brazing technique

CAI Xiaoqiang; WANG Dongpo; WANG Ying; YANG Zhenwen

doi:10.7527/S1000-6893.2021.25006

ACTA AERONAUTICAET ASTRONAUTICA SINICA >

2022 , Vol. 43 >Issue 2: 625006 - 625006

DOI: https://doi.org/10.7527/S1000-6893.2021.25006

Special Topic of Advanced Aeronautical Materials Welding/Joining

Interfacial microstructure and mechanical properties of TiB₂-TiC-SiC ceramics joints fabricated by contact reactive brazing technique

CAI Xiaoqiang ,
WANG Dongpo ,
WANG Ying ,
YANG Zhenwen

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Tianjin Key Laboratory of Advanced Joining Technology, Tianjin University, Tianjin 300072, China

Received date: 2020-11-23

Revised date: 2020-12-21

Online published: 2021-02-08

Supported by

National Natural Science Foundation of China (52175357); Science and Technology Program of Tianjin (19ZXJRGX00100)

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Abstract

Ti-Ni brazing alloy is successfully used to braze the TiB₂-TiC-SiC (TTS) composite ceramic. The influence of change in Ti-Ni brazing alloy composition and brazing time on the interface microstructure and mechanical properties of the joint is studied. The results show that the change of Ti-Ni brazing alloy composition caused the interface reaction to change from a process dominated by the reaction of Ti and TTS ceramic to a process dominated by the reaction of Ni and TTS ceramic. When TTS ceramic is brazed using Ti-24at%Ni brazing alloy, the interface reaction mainly occurred in Ti and TTS ceramic, and the reaction products were TiB₂, TiC and Ti₅Si₃. When TTS ceramic is brazed using Ti-83at%Ni brazing alloy, the interface reaction, especially the reaction with SiC, mainly occurred in Ni and TTS composite ceramics, and the reaction products are mainly Ni₂Si and C. With an increase in the brazing temperature, the continuous Ti₂Ni layer in the brazing seam gradually disappeared, and is replaced by TiB and Ti₅Si₃. In addition, the thickness of the reaction layer increased with the increase of the brazing temperature. The maximum shear strength of the joint achieved at room temperature was 168±10 MPa when the TTS ceramic joint was brazed using Ti-24at%Ni brazing alloy at 1040℃ for 30 min, whereas it was 81±18 MPa when the joint is tested at 800℃.

Key words： titanium diboride; titanium carbide; silicon carbide; brazing; interfacial microstructure; shear strength

Cite this article

CAI Xiaoqiang , WANG Dongpo , WANG Ying , YANG Zhenwen . Interfacial microstructure and mechanical properties of TiB₂-TiC-SiC ceramics joints fabricated by contact reactive brazing technique[J]. ACTA AERONAUTICAET ASTRONAUTICA SINICA, 2022 , 43(2) : 625006 -625006 . DOI: 10.7527/S1000-6893.2021.25006

References

[1] FAHRENHOLTZ W G, HILMAS G E. Ultra-high temperature ceramics:Materials for extreme environments[J].Scripta Materialia, 2017, 129:94-99.
[2] RAN S L, ZHANG L, VAN D B O, et al. Pulsed electric current, in situ synthesis and sintering of textured TiB₂ ceramics[J].Journal of the European Ceramic Society, 2010, 30(4):1043-1047.
[3] HUANG X G, YIN C, HUANG J, et al. Hypervelocity impact of TiB₂-based composites as front bumpers for space shield applications[J].Materials & Design, 2016, 97:473-482.
[4] KONIGSHOFER R, FURNSINN S, STEINKELLNER P, et al. Solid-state properties of hot-pressed TiB₂ ceramics[J].International Journal of Refractory Metals & Hard Materials, 2005, 23(4-6):350-357.
[5] VALLAURI D, ADRIAN I C A, CHRYSANTHOU A. TiC-TiB₂ composites:A review of phase relationships, processing and properties[J].Journal of the European Ceramic Society, 2008, 28(8):1697-1713.
[6] 黄安琪,朱时珍,刘玲, 等. 添加TiB₂对SiC基复相陶瓷显微结构和力学性能的影响[J].硅酸盐学报, 2017, 45(7):924-929. HUANG A Q, ZHU S Z, LIU L, et al. Influence of adding TiB₂ on structure and mechanical properties of SiC-based composite ceramics[J].Journal of the Chinese Ceramic Society, 2017, 45(7):924-929(in Chinese).
[7] DEMESTRAL F, THEVENOT F. Ceramic composites TiB₂-TiC-SiC[J].Journal of Materials Science, 1991, 26(20):5561-5565.
[8] KING D S, HILMAS G E, FAHRENHOLTZ, et al. Plasma arc welding of TiB₂-20vol%TiC[J].Journal of the American Ceramic Society, 2014, 97(1):56-59.
[9] HE P, YANG W Q, LIN T S, et al. Diffusion bonding of ZrB₂-SiC/Nb with in situ synthesized TiB whiskers array[J].Journal of the European Ceramic Society, 2012, 32(16):4447-4454.
[10] 陈铮, 赵其章, 楼宏青, 等. 用Ti/Ni/Ti多层中间层进行Si₃N₄陶瓷的部分瞬间液相连接[J].硅酸盐学报, 1998, 26:34-40. CHEN Z, ZHAO Q Z, LOU H Q, et al. Partial transient liquid phase bonding if Si₃N₄ with Ti/Ni/Ti multi-interlayer[J].Journal of the Chinese Ceramic Society, 1998, 26:34-40(in Chinese).
[11] 张丽霞, 雷敏, 杨智烨, 等. AgCuNiLi钎焊TiC金属陶瓷与GH3128界面结构及接头性能[J].稀有金属材料与工程, 2017, 46(11):3410-3414. ZHANG L X, LEI M, YANG Z Y, et al. Interfacial Microstructure and Properties of TiC Cermet and GH3128 Joint Brazed Using AgCuNiLi[J].Rare Metal Materials and Engineering, 2017, 46(11):3410-3414(in Chinese).
[12] 杨卫岐, 何鹏, 林铁松, 等. 原位TiB增强ZrB₂-SiC接头的界面组织和力学性能[J].稀有金属材料与工程, 2014, 43(4):901-905. YANG W Q, HE P, LIN T S, et al. Interfacial microstructure and properties of in-situ TiB reinforced ZrB₂-SiC joints[J].Rare Metal Materials and Engineering, 2014, 43(4):901-905(in Chinese).
[13] 王颖,夏永红,杨振文, 等. Ti₃SiC₂陶瓷与TC4合金钎焊接头微观组织及性能[J].稀有金属材料与工程, 2019, 48(9):3041-3047. YANG Y, XIA Y H, YANG Z W, et al. Interfacial microstructure and properties of brazed joints of Ti₃SiC₂ ceramic and TC4 alloy[J].Rare Metal Materials and Engineering, 2019, 48(9):3041-3047(in Chinese).
[14] 卞红,胡胜鹏,宋晓国, 等. 钎焊温度对Ti60/AgCu/ZrO₂接头界面组织及性能影响[J].航空学报, 2017, 38(12):421402. BIAN H, HU S P, SONG X G, et al. Effect of brazing temperature on interfacial microstructure and mechanical property of Ti60/AgCu/ZrO₂ joint[J].Acta Aeronautica et Astronautica Sinica, 2017, 38(12):421402(in Chinese).
[15] 牛国宾,王东坡,杨振文, 等. Al₂O₃陶瓷与TiAl合金真空钎焊接头界面组织及性能[J].稀有金属材料与工程, 2017, 46(11):3282-3287. NIU G B, WANG D P, YANG Z W, et al. Interfacial structure and properties of Al₂O₃ ceramic and TiAl alloy brazed joints[J].Rare Metal Materials and Engineering, 2017, 46(11):3282-3287(in Chinese).
[16] SHIUE R K, WU S K, CHEN S Y, et al. Infrared brazing of TiAl intermetallic using BAg-8 braze alloy[J].Acta Materialia, 2003, 51(7):1991-2004.
[17] 徐晓龙,李卓然,刘睿华, 等. ZrB₂-SiC陶瓷复合材料钎焊接头界面组织及性能[J].焊接学报, 2014, 35(1):59-62. XU X L,LI Z R,LIU R H, et al. Microstructure and mechanical properties of ZrB₂-SiC ceramic composite brazed joint[J].Transactions of the China Welding Institution, 2014, 35(1):59-62(in Chinese).
[18] YANG W Q, LIN T S, HE P, et al. Microstructure and mechanical properties of ZrB₂-SiC joints fabricated by a contact-reactive brazing technique with Ti and Ni interlayers[J].Ceramics International, 2014, 40(5):7253-7260.
[19] YANG W Q, XING L L, LIN T S, et al. Microstructural evolution and growth/degradation behavior of in situ TiB whiskers in ZrB₂-SiC joints using Ti/Ni/Ti filler[J].Journal of Alloys and Compounds, 2018, 744:124-131.
[20] 宋昌宝,林铁松,何鹏, 等. Ti-Ni钎料钎焊连接ZrC-SiC复合陶瓷接头的界面组织[J].硅酸盐学报, 2013, 41(3):298-302. SONG C B,LIN T S,HE P, et al. Microstructure of ZrC-SiC composite ceramic joint vacuum brazed with Ti-Ni filler metal[J].Journal of the Chinese Ceramic Society, 2013, 41(3):298-302(in Chinese).
[21] 刘佳音. Pd-Co基钎料钎焊ZrB₂-SiC复合陶瓷的工艺与机理研究[D]. 哈尔滨:哈尔滨工业大学, 2013:28-58. LIU J Y. Brazing progress and mechanism of ZrB₂-SiC composite ceramic using Pd-Co-based filler[D]. Harbin:Harbin Institute of Technology, 2013:28-58(in Chinese).
[22] CACCIAMANI G, RIANI P, VALENZA F, et al. Equilibrium between MB2(M=Ti, Zr, Hf) UHTC and Ni:A thermodynamic database for the B-Hf-Ni-Ti-Zr system[J].Calphad-Computer Coupling of Phase Diagrams and Thermochemistry, 2011, 35(4):601-619.
[23] WEINBERGER C R, THOMPSON G B. Review of phase stability in the group IVB and VB transition-metal carbides[J].Journal of the American Ceramic Society, 2018, 101(10):4401-4424.
[24] ZHANG Y K, LEI Y, MA W H, et al. Preparation of high-purity Ti-Si alloys by vacuum directional solidification[J].Journal of Alloys and Compounds, 2020, 832:153989.
[25] LU W J, ZHANG D, ZHANG X N, et al. Microstructural characterization of TiB in in situ synthesized titanium matrix composites prepared by common casting technique[J].Journal of Alloys and Compounds, 2001, 327(1-2):240-247.
[26] FENG H B, ZHOU Y, JIA D C, et al. Growth mechanism of in situ TiB whiskers in spark plasma sintered TiB/Ti metal matrix composites[J].Crystal Growth & Design, 2006, 6(7):1626-1630.
[27] OTSUKA K, REN X. Physical metallurgy of Ti-Ni-based shape memory alloys[J].Progress in Materials Science, 2005, 50(5):511-678.
[28] YOSHIHITO O, TABAIAN S H, MASAFUMI M. Rates of evaporation in a vacuum in liquid Ni-Ti alloys[J].ISIJ International, 1998, 38(8):789-793.
[29] GOGEBAKAN M, KURSUN C, GUNDUZ K O, et al. Microstructural and mechanical properties of binary Ni-Si eutectic alloys[J].Journal of Alloys and Compounds, 2015, 643:S219-S225.
[30] KEITA A S, WANG Z, SIGLE W, et al. Interfacial reactions of crystalline Ni and amorphous SiC thin films[J].Journal of Materials Science, 2018, 53(9):6681-6697.
[31] SHI H J, CHAI Y D, LI N, et al. Interfacial reaction mechanism of SiC joints joined by pure nickel foil[J].Journal of the European Ceramic Society, 2020, 40(15):5162-5171.
[32] TOPREK D, BELOSEVIC-CAVOR J, KOTESKI V, et al. Ab initio studies of the structural, elastic, electronic and thermal properties of NiTi2 intermetallic[J].Journal of Physics and Chemistry of Solids, 2015, 85:197-205.
[33] CHANDRAN K S R, PANDA K B, SAHAY S S. TiB_w-reinforced Ti composites:Processing, properties, application prospects, and research needs[J].JOM,2004,56(5):42-48.

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