碳纤维增强热固性复合材料(Carbon Fiber Reinforced Thermalsetting Composites,CFRTS)和TC4钛合金具有较高的比强度和比刚性,轻量化效果十分明显,在航空航天、新能源汽车制造中广泛应用。为实现碳CFRTS与TC4钛合金的高强度连接,本文引入“激光清洗+树脂填充”的界面复合调控工艺。在CFRTS和TC4钛合金激光焊接之前,首先采用脉冲光纤激光器对CFRTS表面进行激光清洗处理,去除表层的环氧树脂,使CFRTS中的碳纤维裸露出来;其次利用脉冲光纤激光器对钛合金表面微织构处理,提升焊接时熔融树脂与TC4钛合金的接触面积并形成“咬合”结构;最后在清洗后的CFRTS和钛合金接触面之间添加合适厚度的聚酰胺(PA)树脂,进行激光辅助焊接。本文研究了激光清洗工艺对接头连接强度的影响,通过不同激光清洗工艺参数下CFRTS的表面形貌、PA树脂填充情况、接头断口形貌的对比分析,结果发现:激光清洗CFRTS可以显著增强CFRTS-TC4钛合金接头的强度,最大剪切强度可达23.77MPa。
Carbon fiber reinforced thermalsetting composites (CFRTS) and TC4 titanium alloy have high specific strength and rigidity, and have obvious lightweight effect, which are widely used in aerospace and new energy automobile manufacturing. In order to realize the high-strength connection between CFRTS and TC4 titanium alloy, this paper introduces the interface compound control process of "laser cleaning + resin filling". In order to expose the carbon fiber in the CFRTS, we use a pulsed fiber laser to laser clean the surface of CFRTS to remove the epoxy resin on the surface before laser welding of CFRTS and TC4 titanium alloy firstly; A pulsed fiber laser is used to process the surface microtexture of the titanium alloy to increase the contact area between the molten resin and the TC4 titanium alloy during welding and form an "occlusal" structure secondly; Finally a suitable thickness of polyamide (PA) resin is added into contact surface of the cleaned CFRTS and the titanium alloy for laser-assisted welding.In this paper, the influence of laser cleaning process on the joint connection strength is studied. This paper studies the influence of laser cleaning process on the joint strength of joints. Through the comparative analysis of CFRTS surface morphology, PA resin filling conditions, and joint fracture morphology under different laser cleaning process parameters, it is found that laser cleaning CFRTS can significantly enhance the strength of CFRTS-TC4 titanium alloy joint, the maximum shear strength can reach 23.77MPa.
[1] Kwan-Woo Kim, Dong-Kyu Kim, Byoung-Suhk Kim, et al. Cure behaviors and mechanical properties of carbon fiber-reinforced nylon6/epoxy blended matrix composites. 2016, 112.
[2] Noamen Guermazi, Amira Ben Tarjem, Imen Ksouri, et al. On the durability of
FRP composites for aircraft structures in hygrothermal conditioning. 2016, 85:294-304.
[3] 刘世锋,宋玺,薛彤,马宁,王岩,王立强.钛
合金及钛基复合材料在航空航天的应用和发展[J].航空材料学报,
2020,40(03):77-94.
Liu Shifeng, Song Xi, Xue Tong, MA Ning, WANG Yan, WANG Liqiang.Application and Development of Titanium alloys and Titanium-based composites in Aerospace [J]. Journal of Aeronautical Materials, 2020,40(03):77-94.
[4] 李毅,赵永庆,曾卫东.航空钛合金的应用及发展趋势[J].材料报,2020,34(S1):280-282.
Li Yi, ZHAO Yung-ching, ZENG Weidong.Application and development trend of aerospace titanium alloys [J]. Journal of Materials,202,34(S1):280-282.
[5] Yangjie Zuo, Zengqiang Cao, Yuejie Cao, et al. Dynamic behavior of CFRTS/Ti single-lap pinned joints under longitudinal electromagnetic dynamic loading. 2018, 184:362-371.
[6] Nikolai Kashaev, Volker Ventzke, Stefan Riekehr, et al. Assessment of alternative joining techniques for Ti–6Al–4V/CFRTS hybrid joints regarding tensile and fatigue strength. 2015, 81:73-81.
[7] 高福洋,廖志谦,李文亚.钛及钛合金焊接方法与研究现状[J].航空制造技术,2012(Z2):86-90.
Gao Fuyang, LIAO Zhiqian, LI Wenya.Welding Methods and Research Status of Titanium and titanium alloys [J]. Aeronautical Manufacturing Technology,2012(Z2):86-90.
[8] 程德彬,高福洋.钛合金激光焊接技术研究进展及应用情况[J].材料开发与应用,2020,35(02):87-93.
Cheng Debin, Gao Fuyang.Research progress and Application of laser welding
technology in titanium alloys [J]. Materials Development and Application,202,35(02):87-93.
[9] Junke Jiao, Zifa Xu, Qiang Wang, et al. CFRTP and stainless steel laser joining: Thermal defects analysis and joining parameters optimization. 2018, 103:170-176.
[10] Junke Jiao, Yiyun Ye, Shaohui Jia, et al. CFRTP -Al alloy laser assisted joining with a high speed rotational welding technology. 2020, 127
[11] Junke Jiao, Shaohui Jia, Zifa Xu, et al. Laser direct joining of CFRTP and
aluminium alloy with a hybrid surface pre-treating method. 2019, 173
[12] Adham Al-Sayyad, Julien Bardon, Pierre Hirchenhahn, et al. Aluminum
pretreatment by a laser ablation process: influence of processing parameters on the joint strength of laser welded aluminum – polyamide assemblies. 2018, 74:495-499.
[13] Bu, Li, Yang, et al. Investigation of laser joining process of CFRTP and aluminum alloy. 2020, 35(11):1251-1258.
[14] 贾少辉,贾剑平,焦俊科,徐子法,欧阳文泰,张文武.碳纤维增强热塑性复合材料/铝合金激光搅拌焊接实验及仿真研究[J].中国激光,2019,46(07):109-117.
Jia Shaohui,Jia Jianping,Jiao Junke,Xu Zifa,Ouyang Wentai,Zhang Wenwu.Experiment and simulation of laser stirring welding of carbon fiber reinforced thermoplastic composite material/aluminum alloy[J].China Laser,2019,46(07):109-117.
[15] 叶逸云,贾少辉,焦俊科,束学道.铝合金/碳纤维增强热塑性复合材料激光对接焊研究[J/OL].中国激光:1-14[202003].
Ye Yiyun,Jia Shaohui,Jiao Junke,Shu Xuedao.Study on laser butt welding of aluminum alloy/carbon fiber reinforced thermoplastic composites[J/OL].China Laser:1-14[202003].
[16] Caiwang Tan, Jianhui Su, Baohua Zhu, et al. Effect of scanning speed on laser joining of carbon fiber reinforced PEEK to titanium alloy. 2020, 129
[17] Wang Tao, Xuan Su, Yanbin Chen, et al. Joint formation and fracture characteristics of laser welded CFRP/TC4 joints. 2019, 45:1-8.
[18] Jianhui Su, Caiwang Tan, Zhuolun Wu, et al. Influence of defocus distance on
laser joining of CFRTS to titanium alloy. 2020, 124
[19] Lei Liu, Xiaodong Liu, Liang Kong, et al. Effect of laser surface treatment on surface and bonding properties of carbon fiber reinforced composites. 2019, :1-11.
[20] S. Genna, F. Lambiase, C. Leone. Effect of laser cleaning in Laser Assisted Joining of CFRTS and PC sheets. 2018, 145:206-214.
[21] Armin Palavra, Bruno N. Coelho, Jeff Th. M. de Hosson, et al. Laser surface
treatment for enhanced titanium to carbon fiber-reinforced polymer adhesion. 2017, 39(8):2917-2924.